AlCp* as a directing ligand: C-H and Si-H bond activation at the reactive intermediate [Ni(AlCp*)3]

Tobias Steinke; Christian Gemel; Mirza Cokoja; Manuela Winter; Roland A. Fischer

doi:10.1002/anie.200353114

AlCp* as a directing ligand: C-H and Si-H bond activation at the reactive intermediate [Ni(AlCp*)₃]

Tobias Steinke, Christian Gemel, Mirza Cokoja, Manuela Winter, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

105 Scopus citations

Abstract

As exotic as the title complexes are, and as classic as the concept of generating reactive, unsaturated intermediates [M (ER)_n] is (M = d block metal; E = Al, Ga, In; R = Cp*, C(SiMe₃)₃), there are still many surprises to come. Some of these are shown in the unexpected reactions of [Ni(AlCp*)₃] (see scheme; Cp* = C₅Me₅).

Original language	English
Pages (from-to)	2299-2302
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	43
Issue number	17
DOIs	https://doi.org/10.1002/anie.200353114
State	Published - 19 Apr 2004
Externally published	Yes

Keywords

Aluminum
C-H activation
Group 13 elements
Nickel
Si-H activation

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title = "AlCp* as a directing ligand: C-H and Si-H bond activation at the reactive intermediate [Ni(AlCp*)3]",

abstract = "As exotic as the title complexes are, and as classic as the concept of generating reactive, unsaturated intermediates [M (ER)n] is (M = d block metal; E = Al, Ga, In; R = Cp*, C(SiMe3)3), there are still many surprises to come. Some of these are shown in the unexpected reactions of [Ni(AlCp*)3] (see scheme; Cp* = C5Me5).",

keywords = "Aluminum, C-H activation, Group 13 elements, Nickel, Si-H activation",

author = "Tobias Steinke and Christian Gemel and Mirza Cokoja and Manuela Winter and Fischer, {Roland A.}",

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T1 - AlCp* as a directing ligand

T2 - C-H and Si-H bond activation at the reactive intermediate [Ni(AlCp*)3]

AU - Steinke, Tobias

AU - Gemel, Christian

AU - Cokoja, Mirza

AU - Winter, Manuela

AU - Fischer, Roland A.

PY - 2004/4/19

Y1 - 2004/4/19

N2 - As exotic as the title complexes are, and as classic as the concept of generating reactive, unsaturated intermediates [M (ER)n] is (M = d block metal; E = Al, Ga, In; R = Cp*, C(SiMe3)3), there are still many surprises to come. Some of these are shown in the unexpected reactions of [Ni(AlCp*)3] (see scheme; Cp* = C5Me5).

AB - As exotic as the title complexes are, and as classic as the concept of generating reactive, unsaturated intermediates [M (ER)n] is (M = d block metal; E = Al, Ga, In; R = Cp*, C(SiMe3)3), there are still many surprises to come. Some of these are shown in the unexpected reactions of [Ni(AlCp*)3] (see scheme; Cp* = C5Me5).

KW - Aluminum

KW - C-H activation

KW - Group 13 elements

KW - Nickel

KW - Si-H activation

UR - http://www.scopus.com/inward/record.url?scp=4544349130&partnerID=8YFLogxK

U2 - 10.1002/anie.200353114

DO - 10.1002/anie.200353114

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SN - 1433-7851

VL - 43

SP - 2299

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 17

ER -

AlCp* as a directing ligand: C-H and Si-H bond activation at the reactive intermediate [Ni(AlCp*)₃]

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Keywords

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