[Ag(Sn9-Sn9)]5: A homoleptic silver complex of a dimeric Sn9 Zintl anion

Jian Qiang Wang; Bernhard Wahl; Thomas F. Fässler

doi:10.1002/anie.200907228

[Ag(Sn₉-Sn₉)]⁵: A homoleptic silver complex of a dimeric Sn₉ Zintl anion

Jian Qiang Wang
, Bernhard Wahl
, Thomas F. Fässler

Chair of Inorganic Chemistry with Focus on New Materials

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Finally, a dimeric nonastannide Zintl anion: The cluster anion [Ag(Sn9-Sn9)]5-(1; see picture; blue Sn, red Ag) is obtained from Zintl anion [Sn9]4-by an oxidative coupling reaction. An X-ray structure determination reveals that the Sn - Sn exo bond is also supported by a silver cation. Moreover, 1 is the first cluster consisting only of silver and tin atoms.

Original language	English
Pages (from-to)	6592-6595
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	49
Issue number	37
DOIs	https://doi.org/10.1002/anie.200907228
State	Published - 3 Sep 2010

Keywords

Cluster compounds
Heterometallic complexes
Silver
Tin
Zintl anions

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10.1002/anie.200907228

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title = "[Ag(Sn9-Sn9)]5: A homoleptic silver complex of a dimeric Sn9 Zintl anion",

abstract = "Finally, a dimeric nonastannide Zintl anion: The cluster anion [Ag(Sn9-Sn9)]5-(1; see picture; blue Sn, red Ag) is obtained from Zintl anion [Sn9]4-by an oxidative coupling reaction. An X-ray structure determination reveals that the Sn - Sn exo bond is also supported by a silver cation. Moreover, 1 is the first cluster consisting only of silver and tin atoms.",

keywords = "Cluster compounds, Heterometallic complexes, Silver, Tin, Zintl anions",

author = "Wang, \{Jian Qiang\} and Bernhard Wahl and F{\"a}ssler, \{Thomas F.\}",

year = "2010",

month = sep,

day = "3",

doi = "10.1002/anie.200907228",

language = "English",

volume = "49",

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journal = "Angewandte Chemie International Edition in English",

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publisher = "John Wiley and Sons Ltd",

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T1 - [Ag(Sn9-Sn9)]5

T2 - A homoleptic silver complex of a dimeric Sn9 Zintl anion

AU - Wang, Jian Qiang

AU - Wahl, Bernhard

AU - Fässler, Thomas F.

PY - 2010/9/3

Y1 - 2010/9/3

N2 - Finally, a dimeric nonastannide Zintl anion: The cluster anion [Ag(Sn9-Sn9)]5-(1; see picture; blue Sn, red Ag) is obtained from Zintl anion [Sn9]4-by an oxidative coupling reaction. An X-ray structure determination reveals that the Sn - Sn exo bond is also supported by a silver cation. Moreover, 1 is the first cluster consisting only of silver and tin atoms.

AB - Finally, a dimeric nonastannide Zintl anion: The cluster anion [Ag(Sn9-Sn9)]5-(1; see picture; blue Sn, red Ag) is obtained from Zintl anion [Sn9]4-by an oxidative coupling reaction. An X-ray structure determination reveals that the Sn - Sn exo bond is also supported by a silver cation. Moreover, 1 is the first cluster consisting only of silver and tin atoms.

KW - Cluster compounds

KW - Heterometallic complexes

KW - Silver

KW - Tin

KW - Zintl anions

UR - https://www.scopus.com/pages/publications/77956516665

U2 - 10.1002/anie.200907228

DO - 10.1002/anie.200907228

M3 - Article

AN - SCOPUS:77956516665

SN - 1433-7851

VL - 49

SP - 6592

EP - 6595

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 37

ER -

[Ag(Sn₉-Sn₉)]⁵: A homoleptic silver complex of a dimeric Sn₉ Zintl anion

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Keywords

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