Aggregation-driven reversible formation of conjugated polymers in water

Dainius Janeliunas; Patrick Van Rijn; Job Boekhoven; Christophe B. Minkenberg; Jan H. Van Esch; Rienk Eelkema

doi:10.1002/anie.201209004

Aggregation-driven reversible formation of conjugated polymers in water

Dainius Janeliunas, Patrick Van Rijn, Job Boekhoven, Christophe B. Minkenberg, Jan H. Van Esch, Rienk Eelkema

Delft University of Technology

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Come together: Self-assembly can drive the formation of conjugated imine polymers in water, and stabilization of otherwise unstable imine bonds is used to obtain fully π-conjugated, responsive dynamic covalent polyimines in aqueous environments. Both the optical properties and the aggregate morphology can be tuned by varying the aromatic monomers.

Original language	English
Pages (from-to)	1998-2001
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	52
Issue number	7
DOIs	https://doi.org/10.1002/anie.201209004
State	Published - 11 Feb 2013
Externally published	Yes

Keywords

conjugation
polymers
self-assembly
surfactants
water

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10.1002/anie.201209004

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abstract = "Come together: Self-assembly can drive the formation of conjugated imine polymers in water, and stabilization of otherwise unstable imine bonds is used to obtain fully π-conjugated, responsive dynamic covalent polyimines in aqueous environments. Both the optical properties and the aggregate morphology can be tuned by varying the aromatic monomers.",

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AU - Eelkema, Rienk

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AB - Come together: Self-assembly can drive the formation of conjugated imine polymers in water, and stabilization of otherwise unstable imine bonds is used to obtain fully π-conjugated, responsive dynamic covalent polyimines in aqueous environments. Both the optical properties and the aggregate morphology can be tuned by varying the aromatic monomers.

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KW - polymers

KW - self-assembly

KW - surfactants

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Aggregation-driven reversible formation of conjugated polymers in water

Abstract

Keywords

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