Adsorption of methanol on MCM-36 derivatives with strong acid and base sites

R. Schenkel; J. O. Barth; J. Kornatowski; A. Jentys; J. A. Lercher

doi:10.1016/s0167-2991(04)80683-9

Adsorption of methanol on MCM-36 derivatives with strong acid and base sites

R. Schenkel, J. O. Barth, J. Kornatowski, A. Jentys, J. A. Lercher

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The sorption of methanol on MCM-22 and MCM-36 materials was studied using mainly IR spectroscopy. MCM-36 materials pillared with (mixed) oxides such as SiO₂, Al₂O₃, MgO-Al₂O₃, and MgO-Al₂O₃-SiO₂, exhibit widely varying acid-base properties. Methanol is associatively adsorbed on Brønsted acid sites in the zeolitic micropores and associatively and dissociatively on acid and base sites in the mesopores. Lewis acid/base sites are responsible for dissociative adsorption. Stable formates were only formed upon heating MgO-Al₂O₃-MCM-36 saturated with methanol.

Original language	English
Pages (from-to)	1598-1605
Number of pages	8
Journal	Studies in Surface Science and Catalysis
Volume	154 B
DOIs	https://doi.org/10.1016/s0167-2991(04)80683-9
State	Published - 2004

Keywords

(Mixed) oxide pillared MCM-36
IR studies
MCM-22
MCM-36
Methanol adsorption

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10.1016/s0167-2991(04)80683-9

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title = "Adsorption of methanol on MCM-36 derivatives with strong acid and base sites",

abstract = "The sorption of methanol on MCM-22 and MCM-36 materials was studied using mainly IR spectroscopy. MCM-36 materials pillared with (mixed) oxides such as SiO2, Al2O3, MgO-Al2O3, and MgO-Al2O3-SiO2, exhibit widely varying acid-base properties. Methanol is associatively adsorbed on Br{\o}nsted acid sites in the zeolitic micropores and associatively and dissociatively on acid and base sites in the mesopores. Lewis acid/base sites are responsible for dissociative adsorption. Stable formates were only formed upon heating MgO-Al2O3-MCM-36 saturated with methanol.",

keywords = "(Mixed) oxide pillared MCM-36, IR studies, MCM-22, MCM-36, Methanol adsorption",

author = "R. Schenkel and Barth, {J. O.} and J. Kornatowski and A. Jentys and Lercher, {J. A.}",

note = "Funding Information: The work was partially supported by the Deutsche Forschungsgemeinschaft (DFG).",

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doi = "10.1016/s0167-2991(04)80683-9",

language = "English",

volume = "154 B",

pages = "1598--1605",

journal = "Studies in Surface Science and Catalysis",

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TY - JOUR

T1 - Adsorption of methanol on MCM-36 derivatives with strong acid and base sites

AU - Schenkel, R.

AU - Barth, J. O.

AU - Kornatowski, J.

AU - Jentys, A.

AU - Lercher, J. A.

N1 - Funding Information: The work was partially supported by the Deutsche Forschungsgemeinschaft (DFG).

PY - 2004

Y1 - 2004

N2 - The sorption of methanol on MCM-22 and MCM-36 materials was studied using mainly IR spectroscopy. MCM-36 materials pillared with (mixed) oxides such as SiO2, Al2O3, MgO-Al2O3, and MgO-Al2O3-SiO2, exhibit widely varying acid-base properties. Methanol is associatively adsorbed on Brønsted acid sites in the zeolitic micropores and associatively and dissociatively on acid and base sites in the mesopores. Lewis acid/base sites are responsible for dissociative adsorption. Stable formates were only formed upon heating MgO-Al2O3-MCM-36 saturated with methanol.

AB - The sorption of methanol on MCM-22 and MCM-36 materials was studied using mainly IR spectroscopy. MCM-36 materials pillared with (mixed) oxides such as SiO2, Al2O3, MgO-Al2O3, and MgO-Al2O3-SiO2, exhibit widely varying acid-base properties. Methanol is associatively adsorbed on Brønsted acid sites in the zeolitic micropores and associatively and dissociatively on acid and base sites in the mesopores. Lewis acid/base sites are responsible for dissociative adsorption. Stable formates were only formed upon heating MgO-Al2O3-MCM-36 saturated with methanol.

KW - (Mixed) oxide pillared MCM-36

KW - IR studies

KW - MCM-22

KW - MCM-36

KW - Methanol adsorption

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U2 - 10.1016/s0167-2991(04)80683-9

DO - 10.1016/s0167-2991(04)80683-9

M3 - Article

AN - SCOPUS:11844286283

SN - 0167-2991

VL - 154 B

SP - 1598

EP - 1605

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Adsorption of methanol on MCM-36 derivatives with strong acid and base sites

Abstract

Keywords

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