Adsorption and desorption of CO on Ru(0 0 0 1): A comprehensive analysis

S. H. Payne; J. S. McEwen; H. J. Kreuzer; D. Menzel

doi:10.1016/j.susc.2005.07.031

Adsorption and desorption of CO on Ru(0 0 0 1): A comprehensive analysis

S. H. Payne, J. S. McEwen, H. J. Kreuzer, D. Menzel

Chair of Experimental Physics

Dalhousie University

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

A comprehensive theory of the adsorption of CO on Ru(0 0 0 1) is developed to describe equilibrium properties and the adsorption and desorption kinetics. The basis is a multi-site lattice gas model with site exclusion and lateral interactions between CO molecules out to second neighbour unit cells. The theory reproduces the coverage and temperature dependence of coverage isobars, heat of adsorption, structural data, sticking coefficients, and isothermal and temperature-programmed desorption rates in a consistent manner.

Original language	English
Pages (from-to)	240-262
Number of pages	23
Journal	Surface Science
Volume	594
Issue number	1-3
DOIs	https://doi.org/10.1016/j.susc.2005.07.031
State	Published - 1 Dec 2005

Keywords

Adsorption kinetics
Carbon monoxide
Equilibrium thermodynamics and statistical mechanics
Models of surface kinetics
Ruthenium
Sticking
Thermal desorption

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10.1016/j.susc.2005.07.031

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title = "Adsorption and desorption of CO on Ru(0 0 0 1): A comprehensive analysis",

abstract = "A comprehensive theory of the adsorption of CO on Ru(0 0 0 1) is developed to describe equilibrium properties and the adsorption and desorption kinetics. The basis is a multi-site lattice gas model with site exclusion and lateral interactions between CO molecules out to second neighbour unit cells. The theory reproduces the coverage and temperature dependence of coverage isobars, heat of adsorption, structural data, sticking coefficients, and isothermal and temperature-programmed desorption rates in a consistent manner.",

keywords = "Adsorption kinetics, Carbon monoxide, Equilibrium thermodynamics and statistical mechanics, Models of surface kinetics, Ruthenium, Sticking, Thermal desorption",

author = "Payne, {S. H.} and McEwen, {J. S.} and Kreuzer, {H. J.} and D. Menzel",

note = "Funding Information: The work at Dalhousie was supported by grants from NSERC and the US Office of Naval Research. ",

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T1 - Adsorption and desorption of CO on Ru(0 0 0 1)

T2 - A comprehensive analysis

AU - Payne, S. H.

AU - McEwen, J. S.

AU - Kreuzer, H. J.

AU - Menzel, D.

N1 - Funding Information: The work at Dalhousie was supported by grants from NSERC and the US Office of Naval Research.

PY - 2005/12/1

Y1 - 2005/12/1

N2 - A comprehensive theory of the adsorption of CO on Ru(0 0 0 1) is developed to describe equilibrium properties and the adsorption and desorption kinetics. The basis is a multi-site lattice gas model with site exclusion and lateral interactions between CO molecules out to second neighbour unit cells. The theory reproduces the coverage and temperature dependence of coverage isobars, heat of adsorption, structural data, sticking coefficients, and isothermal and temperature-programmed desorption rates in a consistent manner.

AB - A comprehensive theory of the adsorption of CO on Ru(0 0 0 1) is developed to describe equilibrium properties and the adsorption and desorption kinetics. The basis is a multi-site lattice gas model with site exclusion and lateral interactions between CO molecules out to second neighbour unit cells. The theory reproduces the coverage and temperature dependence of coverage isobars, heat of adsorption, structural data, sticking coefficients, and isothermal and temperature-programmed desorption rates in a consistent manner.

KW - Adsorption kinetics

KW - Carbon monoxide

KW - Equilibrium thermodynamics and statistical mechanics

KW - Models of surface kinetics

KW - Ruthenium

KW - Sticking

KW - Thermal desorption

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DO - 10.1016/j.susc.2005.07.031

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AN - SCOPUS:27144440376

SN - 0039-6028

VL - 594

SP - 240

EP - 262

JO - Surface Science

JF - Surface Science

IS - 1-3

ER -

Adsorption and desorption of CO on Ru(0 0 0 1): A comprehensive analysis

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Keywords

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