Addressing association entropy by reconstructing guanidinium anchor groups for anion binding: Design, synthesis and host-guest binding studies in polar and protic solutions

Keyphrases

• Protic 100%
• Anchoring Group 100%
• Guanidinium 100%
• Binding Studies 100%
• Host-guest Binding 100%
• Anion Binding 100%
• Methanol 66%
• Bicyclol 66%
• Carboxylate 66%
• Guanidinium Group 66%
• Acetonitrile 66%
• Phosphate 66%
• NMR Spectroscopy 33%
• Proton 33%
• Oxoanions 33%
• Pyrimidine 33%
• X-ray Crystal Structure 33%
• Ion Pairs 33%
• Molecular Modeling 33%
• Titration 33%
• By Design 33%
• Binding Affinity 33%
• Sulfuric Acid 33%
• Isothermal Titration Calorimetry 33%
• Phosphinate 33%
• Entropic Factors 33%
• Carboxamide 33%
• Bona Fide 33%
• Convergent Strategy 33%
• Host-guest 33%
• Binding Selectivity 33%
• Positive Entropy 33%
• Amidation 33%
• Dihydrogen Phosphate 33%
• Phthalates 33%
• Binding Enthalpy 33%
• Enthalpic Interaction 33%
• 4-nitrobenzoate 33%
• Tetraester 33%
• Squarate 33%
• Hydrogen Bonds (H-bonds) 33%

Chemistry

• Anion 100%
• Guanidinium 100%
• Association Entropy 100%
• Guanidine 100%
• Methanol 40%
• Acetonitrile 40%
• Carboxylic Acid 40%
• Crystal Structure 20%
• Complexation 20%
• Energetics 20%
• Hydrogen Bonding 20%
• Oxoanion 20%
• Enthalpy 20%
• Phosphinate 20%
• Kd 20%
• Carboxamide 20%
• Sulfate 20%
• Isothermal Titration Calorimetry 20%
• Hydrogen 20%
• NMR Spectroscopy 20%
• Squarate 20%
• Dihydrogenphosphate 20%
• Nitrobenzoate 20%
• Phthalate 20%
• Molecular Model 20%
• amidation 20%