aci‐Nitrodiphenylmethane: A Hydrogen‐Bonded Dimer

Hans Bock; Rüdiger Dienelt; Holger Schödel; Zdenek Havlas; Eberhardt Herdtweck; Wolfgang A. Herrmann

doi:10.1002/anie.199317581

aci‐Nitrodiphenylmethane: A Hydrogen‐Bonded Dimer

Hans Bock
, Rüdiger Dienelt
, Holger Schödel
, Zdenek Havlas
, Eberhardt Herdtweck
, Wolfgang A. Herrmann

Technical University of Munich

Johann Wolfgang Goethe University
Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic
Technical University of Munich

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

The first structurally characterized aci‐nitromethane, the title compound, was obtained by acidifying its sodium salt. It crystallized as the hydrogen‐bonded dimer 1. The eight‐membered ring that includes the H bonds has a chair conformation. According to quantum mechanical calculations, the cooperative effect on the formation of the H‐bonded dimer is 40%. (Figure Presented.)

Original language	English
Pages (from-to)	1758-1760
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	32
Issue number	12
DOIs	https://doi.org/10.1002/anie.199317581
State	Published - Dec 1993

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title = "aci‐Nitrodiphenylmethane: A Hydrogen‐Bonded Dimer",

abstract = "The first structurally characterized aci‐nitromethane, the title compound, was obtained by acidifying its sodium salt. It crystallized as the hydrogen‐bonded dimer 1. The eight‐membered ring that includes the H bonds has a chair conformation. According to quantum mechanical calculations, the cooperative effect on the formation of the H‐bonded dimer is 40\%. (Figure Presented.)",

author = "Hans Bock and R{\"u}diger Dienelt and Holger Sch{\"o}del and Zdenek Havlas and Eberhardt Herdtweck and Herrmann, \{Wolfgang A.\}",

year = "1993",

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doi = "10.1002/anie.199317581",

language = "English",

volume = "32",

pages = "1758--1760",

journal = "Angewandte Chemie International Edition in English",

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TY - JOUR

T1 - aci‐Nitrodiphenylmethane

T2 - A Hydrogen‐Bonded Dimer

AU - Bock, Hans

AU - Dienelt, Rüdiger

AU - Schödel, Holger

AU - Havlas, Zdenek

AU - Herdtweck, Eberhardt

AU - Herrmann, Wolfgang A.

PY - 1993/12

Y1 - 1993/12

N2 - The first structurally characterized aci‐nitromethane, the title compound, was obtained by acidifying its sodium salt. It crystallized as the hydrogen‐bonded dimer 1. The eight‐membered ring that includes the H bonds has a chair conformation. According to quantum mechanical calculations, the cooperative effect on the formation of the H‐bonded dimer is 40%. (Figure Presented.)

AB - The first structurally characterized aci‐nitromethane, the title compound, was obtained by acidifying its sodium salt. It crystallized as the hydrogen‐bonded dimer 1. The eight‐membered ring that includes the H bonds has a chair conformation. According to quantum mechanical calculations, the cooperative effect on the formation of the H‐bonded dimer is 40%. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/33748845856

U2 - 10.1002/anie.199317581

DO - 10.1002/anie.199317581

M3 - Article

AN - SCOPUS:33748845856

SN - 0570-0833

VL - 32

SP - 1758

EP - 1760

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 12

ER -

aci‐Nitrodiphenylmethane: A Hydrogen‐Bonded Dimer

Abstract

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