Accelerated aging characterization of lithium-ion cells: Limitation of arrhenius dependency

Tanja Gewald, Markus Lienkamp, Dirk Lehmkuhl, Alexander Hahn

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

7 Scopus citations

Abstract

Cell selection is a mandatory first step for the design of automotive battery systems. Thereby, aging characterization enables quantification of aging-related effects at an early stage. For aging characterization in industrial applications, an accelerated implementation is required. Applied methods for acceleration must not alter the composition of aging, and therefore must not initiate different aging mechanisms in comparison to the non-accelerated reference case. With regard to temperature dependence of calendar aging, this requirement of mechanism consistency corresponds to the validity of the Arrhenius dependency. This paper presents the results of a test series on calendar aging at temperatures ranging from 25°C to 80°C. Mechanism consistency is investigated using Differential Voltage Analysis (DVA), proving additional aging mechanisms beyond 60°C. In conclusion, the limitations of Arrhenius dependency for the investigated cells are discussed.

Original languageEnglish
Title of host publication2019 14th International Conference on Ecological Vehicles and Renewable Energies, EVER 2019
PublisherInstitute of Electrical and Electronics Engineers Inc.
ISBN (Electronic)9781728137032
DOIs
StatePublished - May 2019
Event14th International Conference on Ecological Vehicles and Renewable Energies, EVER 2019 - Monte-Carlo, Monaco
Duration: 8 May 201910 May 2019

Publication series

Name2019 14th International Conference on Ecological Vehicles and Renewable Energies, EVER 2019

Conference

Conference14th International Conference on Ecological Vehicles and Renewable Energies, EVER 2019
Country/TerritoryMonaco
CityMonte-Carlo
Period8/05/1910/05/19

Keywords

  • Aging mechanisms
  • Arrhenius
  • Batteries
  • Calendar aging
  • Differential voltage analysis.
  • Lithium-ion cell
  • Temperature dependency

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