Absorption and fluorescence of Tl atoms in rare gas matrices

Brent E. Wurfel; Anton Thoma; Günter Schallmoser; Andreas Lammers; Vladimir E. Bondybey

doi:10.1063/1.466793

Absorption and fluorescence of Tl atoms in rare gas matrices

Brent E. Wurfel, Anton Thoma, Günter Schallmoser, Andreas Lammers, Vladimir E. Bondybey

Chair of Physical Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Tl containing Ar, Kr, and Xe matrices were produced by electrode sputtering in a self-igniting pulsed-discharge unit. The absorption and laser-induced fluorescence spectra of the thallium atoms have been investigated. The results are compared with our recent observations of gas phase diatomic thallium-rare gas (Tl-Rg) clusters. The observed linewidths, shifts, and relaxation dynamics are qualitatively interpreted on the basis of the pairwise Tl-Rg interaction potentials.

Original language	English
Pages (from-to)	8003-8009
Number of pages	7
Journal	Journal of Chemical Physics
Volume	100
Issue number	11
DOIs	https://doi.org/10.1063/1.466793
State	Published - 1994

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abstract = "Tl containing Ar, Kr, and Xe matrices were produced by electrode sputtering in a self-igniting pulsed-discharge unit. The absorption and laser-induced fluorescence spectra of the thallium atoms have been investigated. The results are compared with our recent observations of gas phase diatomic thallium-rare gas (Tl-Rg) clusters. The observed linewidths, shifts, and relaxation dynamics are qualitatively interpreted on the basis of the pairwise Tl-Rg interaction potentials.",

author = "Wurfel, {Brent E.} and Anton Thoma and G{\"u}nter Schallmoser and Andreas Lammers and Bondybey, {Vladimir E.}",

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journal = "Journal of Chemical Physics",

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T1 - Absorption and fluorescence of Tl atoms in rare gas matrices

AU - Wurfel, Brent E.

AU - Thoma, Anton

AU - Schallmoser, Günter

AU - Lammers, Andreas

AU - Bondybey, Vladimir E.

PY - 1994

Y1 - 1994

N2 - Tl containing Ar, Kr, and Xe matrices were produced by electrode sputtering in a self-igniting pulsed-discharge unit. The absorption and laser-induced fluorescence spectra of the thallium atoms have been investigated. The results are compared with our recent observations of gas phase diatomic thallium-rare gas (Tl-Rg) clusters. The observed linewidths, shifts, and relaxation dynamics are qualitatively interpreted on the basis of the pairwise Tl-Rg interaction potentials.

AB - Tl containing Ar, Kr, and Xe matrices were produced by electrode sputtering in a self-igniting pulsed-discharge unit. The absorption and laser-induced fluorescence spectra of the thallium atoms have been investigated. The results are compared with our recent observations of gas phase diatomic thallium-rare gas (Tl-Rg) clusters. The observed linewidths, shifts, and relaxation dynamics are qualitatively interpreted on the basis of the pairwise Tl-Rg interaction potentials.

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U2 - 10.1063/1.466793

DO - 10.1063/1.466793

M3 - Article

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 11

ER -

Absorption and fluorescence of Tl atoms in rare gas matrices

Abstract

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