A Triply Bridged Dicobalt Complex with Odd Number of Electrons (Co 21+)

Hans Helnz Karsch; Beatrix Milewski‐Mahrla

doi:10.1002/anie.198108141

A Triply Bridged Dicobalt Complex with Odd Number of Electrons (Co 21+)

Hans Helnz Karsch, Beatrix Milewski‐Mahrla

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Technical University of Munich

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7 Scopus citations

Abstract

The spontaneous formation of dicobalt complex 3 with the “mixed” oxidation state Co 21+ was observed in the reaction of the Co⁰ complex 1 with the bis(phosphane) 2. Other dinuclear complexes of this type with an odd number of electrons are only accessible in exceptional cases. (Figure Presented.)

Original language	English
Pages (from-to)	814-815
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	20
Issue number	9
DOIs	https://doi.org/10.1002/anie.198108141
State	Published - Sep 1981

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title = "A Triply Bridged Dicobalt Complex with Odd Number of Electrons (Co 21+)",

abstract = "The spontaneous formation of dicobalt complex 3 with the “mixed” oxidation state Co 21+ was observed in the reaction of the Co0 complex 1 with the bis(phosphane) 2. Other dinuclear complexes of this type with an odd number of electrons are only accessible in exceptional cases. (Figure Presented.)",

author = "Karsch, {Hans Helnz} and Beatrix Milewski‐Mahrla",

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N2 - The spontaneous formation of dicobalt complex 3 with the “mixed” oxidation state Co 21+ was observed in the reaction of the Co0 complex 1 with the bis(phosphane) 2. Other dinuclear complexes of this type with an odd number of electrons are only accessible in exceptional cases. (Figure Presented.)

AB - The spontaneous formation of dicobalt complex 3 with the “mixed” oxidation state Co 21+ was observed in the reaction of the Co0 complex 1 with the bis(phosphane) 2. Other dinuclear complexes of this type with an odd number of electrons are only accessible in exceptional cases. (Figure Presented.)

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M3 - Article

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SN - 0570-0833

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 9

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A Triply Bridged Dicobalt Complex with Odd Number of Electrons (Co 21+)

Abstract

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