A surface organometallic approach to the synthesis of rhenium-based catalysts for the metathesis of olefins: CH3ReO3/Nb2O5

R. Buffon; A. Auroux; F. Lefebvre; M. Leconte; A. Choplin; J. M. Basset; W. A. Herrmann

doi:10.1016/0304-5102(92)80165-D

A surface organometallic approach to the synthesis of rhenium-based catalysts for the metathesis of olefins: CH₃ReO₃/Nb₂O₅

R. Buffon, A. Auroux, F. Lefebvre, M. Leconte, A. Choplin, J. M. Basset, W. A. Herrmann

Technical University of Munich

Université Claude Bernard Lyon 1

Research output: Contribution to journal › Article › peer-review

76 Scopus citations

Abstract

The reaction of methyltrioxorhenium with the surface of niobium oxide leads to an active catalyst for the metathesis of acyclic olefins. The activity is related to the niobia surface acidity and to a methylrhenium surface species that resonates at 25 ppm on the ¹³C MAS NMR spectrum.

Original language	English
Pages (from-to)	287-295
Number of pages	9
Journal	Journal of Molecular Catalysis
Volume	76
Issue number	1-3
DOIs	https://doi.org/10.1016/0304-5102(92)80165-D
State	Published - 15 Oct 1992

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title = "A surface organometallic approach to the synthesis of rhenium-based catalysts for the metathesis of olefins: CH3ReO3/Nb2O5",

abstract = "The reaction of methyltrioxorhenium with the surface of niobium oxide leads to an active catalyst for the metathesis of acyclic olefins. The activity is related to the niobia surface acidity and to a methylrhenium surface species that resonates at 25 ppm on the 13C MAS NMR spectrum.",

author = "R. Buffon and A. Auroux and F. Lefebvre and M. Leconte and A. Choplin and Basset, {J. M.} and Herrmann, {W. A.}",

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T1 - A surface organometallic approach to the synthesis of rhenium-based catalysts for the metathesis of olefins

T2 - CH3ReO3/Nb2O5

AU - Buffon, R.

AU - Auroux, A.

AU - Lefebvre, F.

AU - Leconte, M.

AU - Choplin, A.

AU - Basset, J. M.

AU - Herrmann, W. A.

PY - 1992/10/15

Y1 - 1992/10/15

N2 - The reaction of methyltrioxorhenium with the surface of niobium oxide leads to an active catalyst for the metathesis of acyclic olefins. The activity is related to the niobia surface acidity and to a methylrhenium surface species that resonates at 25 ppm on the 13C MAS NMR spectrum.

AB - The reaction of methyltrioxorhenium with the surface of niobium oxide leads to an active catalyst for the metathesis of acyclic olefins. The activity is related to the niobia surface acidity and to a methylrhenium surface species that resonates at 25 ppm on the 13C MAS NMR spectrum.

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DO - 10.1016/0304-5102(92)80165-D

M3 - Article

AN - SCOPUS:0026941914

SN - 0304-5102

VL - 76

SP - 287

EP - 295

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

IS - 1-3

ER -

A surface organometallic approach to the synthesis of rhenium-based catalysts for the metathesis of olefins: CH₃ReO₃/Nb₂O₅

Abstract

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