A straightforward preparation of acetonitrile ligated silver perfluoroalkoxy aluminate [Ag(NCCH3)4][Al{OC(CF3)3}4]

Yang Li; Fritz E. Kühn

doi:10.1016/j.jorganchem.2008.04.025

A straightforward preparation of acetonitrile ligated silver perfluoroalkoxy aluminate [Ag(NCCH₃)₄][Al{OC(CF₃)₃}₄]

Yang Li, Fritz E. Kühn

Associate Professorship of Molecular Catalysis

Technical University of Munich

Research output: Contribution to journal › Short survey › peer-review

14 Scopus citations

Abstract

Acetonitrile ligated silver perfluoroalkoxy aluminate can be applied as versatile anion transfer reagent for several complexes with weakly coordinating counter anions. Its synthesis, however, is not as inexpensive and easy as it would be desirable. Accordingly, a new and straightforward synthesis for this useful compound, avoiding the use of expensive AgF and an ultrasonic bath has been developed, affording 90% yield.

Original language	English
Pages (from-to)	2465-2467
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	693
Issue number	14
DOIs	https://doi.org/10.1016/j.jorganchem.2008.04.025
State	Published - 1 Jul 2008

Keywords

Alkoxides
Aluminum
Silver
Sodium
Weakly coordinating anions

Access to Document

10.1016/j.jorganchem.2008.04.025

Cite this

@article{c2c52fbf2ab041f8af9bde8ac1fa6642,

title = "A straightforward preparation of acetonitrile ligated silver perfluoroalkoxy aluminate [Ag(NCCH3)4][Al{OC(CF3)3}4]",

abstract = "Acetonitrile ligated silver perfluoroalkoxy aluminate can be applied as versatile anion transfer reagent for several complexes with weakly coordinating counter anions. Its synthesis, however, is not as inexpensive and easy as it would be desirable. Accordingly, a new and straightforward synthesis for this useful compound, avoiding the use of expensive AgF and an ultrasonic bath has been developed, affording 90% yield.",

keywords = "Alkoxides, Aluminum, Silver, Sodium, Weakly coordinating anions",

author = "Yang Li and K{\"u}hn, {Fritz E.}",

year = "2008",

month = jul,

day = "1",

doi = "10.1016/j.jorganchem.2008.04.025",

language = "English",

volume = "693",

pages = "2465--2467",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "14",

}

TY - JOUR

T1 - A straightforward preparation of acetonitrile ligated silver perfluoroalkoxy aluminate [Ag(NCCH3)4][Al{OC(CF3)3}4]

AU - Li, Yang

AU - Kühn, Fritz E.

PY - 2008/7/1

Y1 - 2008/7/1

N2 - Acetonitrile ligated silver perfluoroalkoxy aluminate can be applied as versatile anion transfer reagent for several complexes with weakly coordinating counter anions. Its synthesis, however, is not as inexpensive and easy as it would be desirable. Accordingly, a new and straightforward synthesis for this useful compound, avoiding the use of expensive AgF and an ultrasonic bath has been developed, affording 90% yield.

AB - Acetonitrile ligated silver perfluoroalkoxy aluminate can be applied as versatile anion transfer reagent for several complexes with weakly coordinating counter anions. Its synthesis, however, is not as inexpensive and easy as it would be desirable. Accordingly, a new and straightforward synthesis for this useful compound, avoiding the use of expensive AgF and an ultrasonic bath has been developed, affording 90% yield.

KW - Alkoxides

KW - Aluminum

KW - Silver

KW - Sodium

KW - Weakly coordinating anions

UR - http://www.scopus.com/inward/record.url?scp=46549083013&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2008.04.025

DO - 10.1016/j.jorganchem.2008.04.025

M3 - Short survey

AN - SCOPUS:46549083013

SN - 0022-328X

VL - 693

SP - 2465

EP - 2467

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 14

ER -

A straightforward preparation of acetonitrile ligated silver perfluoroalkoxy aluminate [Ag(NCCH₃)₄][Al{OC(CF₃)₃}₄]

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this