A Silica Bilayer Supported on Ru(0001): Following the Crystalline-to Vitreous Transformation in Real Time with Spectro-microscopy

Hagen W. Klemm, Mauricio J. Prieto, Feng Xiong, Ghada B. Hassine, Markus Heyde, Dietrich Menzel, Marek Sierka, Thomas Schmidt, Hans Joachim Freund

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The crystalline-to-vitreous phase transformation of a SiO2 bilayer supported on Ru(0001) was studied by time-dependent LEED, local XPS, and DFT calculations. The silica bilayer system has parallels to 3D silica glass and can be used to understand the mechanism of the disorder transition. DFT simulations show that the formation of a Stone–Wales-type of defect follows a complex mechanism, where the two layers show decoupled behavior in terms of chemical bond rearrangements. The calculated activation energy of the rate-determining step for the formation of a Stone—Wales-type of defect (4.3 eV) agrees with the experimental value. Charge transfer between SiO2 bilayer and Ru(0001) support lowers the activation energy for breaking the Si−O bond compared to the unsupported film. Pre-exponential factors obtained in UHV and in O2 atmospheres differ significantly, suggesting that the interfacial ORu underneath the SiO2 bilayer plays a role on how the disordering propagates within the film.

Original languageEnglish
Pages (from-to)10587-10593
Number of pages7
JournalAngewandte Chemie International Edition in English
Volume59
Issue number26
DOIs
StatePublished - 22 Jun 2020

Keywords

  • crystalline bilayers
  • phase transitions
  • polymorphs
  • silica bilayers
  • vitreous bilayers

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