A short Bi=Bi bond supported by a metalloid group 13 ligand

Ganesan Prabusankar; Christian Gemel; Pattiyil Parameswaran; Charity Flener; Gernot Frenking; Roland A. Fischer

doi:10.1002/anie.200902172

A short Bi=Bi bond supported by a metalloid group 13 ligand

Ganesan Prabusankar, Christian Gemel, Pattiyil Parameswaran, Charity Flener, Gernot Frenking, Roland A. Fischer

Research output: Contribution to journal › Article › peer-review

78 Scopus citations

Abstract

Bismuth goes GaGa: Dibismuthenes are derived from commercially available bismuth(III) triflate or aryloxide salts by employing [Ga(ddp)] (ddp=CH[MeC(2,6-iPr₂C₆H₃)N]₂) as an efficient reducing agent and trapping ligand. Apart from the shortest bismuth-bismuth bonds known to date, the compounds demonstrate the unique synthetic potential in main-group chemistry of lowcoordinate Group 13 compounds analogous to N-heterocyclic carbenes.

Original language	English
Pages (from-to)	5526-5529
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	48
Issue number	30
DOIs	https://doi.org/10.1002/anie.200902172
State	Published - 13 Jul 2009
Externally published	Yes

Keywords

Bismuth
Gallium
Main-group elements
Metal-metal interactions
Reduction

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10.1002/anie.200902172

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abstract = "Bismuth goes GaGa: Dibismuthenes are derived from commercially available bismuth(III) triflate or aryloxide salts by employing [Ga(ddp)] (ddp=CH[MeC(2,6-iPr2C6H3)N]2) as an efficient reducing agent and trapping ligand. Apart from the shortest bismuth-bismuth bonds known to date, the compounds demonstrate the unique synthetic potential in main-group chemistry of lowcoordinate Group 13 compounds analogous to N-heterocyclic carbenes.",

keywords = "Bismuth, Gallium, Main-group elements, Metal-metal interactions, Reduction",

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AU - Prabusankar, Ganesan

AU - Gemel, Christian

AU - Parameswaran, Pattiyil

AU - Flener, Charity

AU - Frenking, Gernot

AU - Fischer, Roland A.

PY - 2009/7/13

Y1 - 2009/7/13

N2 - Bismuth goes GaGa: Dibismuthenes are derived from commercially available bismuth(III) triflate or aryloxide salts by employing [Ga(ddp)] (ddp=CH[MeC(2,6-iPr2C6H3)N]2) as an efficient reducing agent and trapping ligand. Apart from the shortest bismuth-bismuth bonds known to date, the compounds demonstrate the unique synthetic potential in main-group chemistry of lowcoordinate Group 13 compounds analogous to N-heterocyclic carbenes.

AB - Bismuth goes GaGa: Dibismuthenes are derived from commercially available bismuth(III) triflate or aryloxide salts by employing [Ga(ddp)] (ddp=CH[MeC(2,6-iPr2C6H3)N]2) as an efficient reducing agent and trapping ligand. Apart from the shortest bismuth-bismuth bonds known to date, the compounds demonstrate the unique synthetic potential in main-group chemistry of lowcoordinate Group 13 compounds analogous to N-heterocyclic carbenes.

KW - Bismuth

KW - Gallium

KW - Main-group elements

KW - Metal-metal interactions

KW - Reduction

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 30

ER -

A short Bi=Bi bond supported by a metalloid group 13 ligand

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Keywords

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