A selective palladium-catalyzed carbonylative arylation of aryl ketones to give vinylbenzoate compounds

Johannes Schranck, Anis Tlili, Helfried Neumann, Pamela G. Alsabeh, Mark Stradiotto, Matthias Beller

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

Preparation of enols: When treated with [{Pd(cinnamyl)Cl} 2]/cataCXium A (nBuPAd2, Ad=adamantyl) under an atmosphere of CO, aryl ketones react with aryl halides in a carbonylative C-O coupling reaction to form (Z)-vinyl benzoates (see scheme).

Original languageEnglish
Pages (from-to)15592-15597
Number of pages6
JournalChemistry - A European Journal
Volume18
Issue number49
DOIs
StatePublished - 3 Dec 2012
Externally publishedYes

Keywords

  • carbonylation
  • enols
  • homogeneous catalysis
  • palladium
  • vinyl esters

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