A selective and practical synthesis of nitroolefins

Irina Jovel, Saisuree Prateeptongkum, Ralf Jackstell, Nadine Vogl, Christoph Weckbecker, Matthias Beller

Research output: Contribution to journalArticlepeer-review

59 Scopus citations

Abstract

A straightforward and general synthesis of nitroolefins from nitric oxide (NO) and olefins is presented. The direct nitration of aromatic olefins, allyl compounds, and acrylic acid derivatives proceeds smoothly at room temperature with high regioselectivity and good yields. The advantages of this novel procedure compared to established nitration procedures are demonstrated.

Original languageEnglish
Pages (from-to)2493-2497
Number of pages5
JournalAdvanced Synthesis and Catalysis
Volume350
Issue number16
DOIs
StatePublished - 3 Nov 2008
Externally publishedYes

Keywords

  • Nitration
  • Nitric oxide (NO)
  • Nitroolefins
  • Olefins

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