A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII)-Cis-and trans-coordination of the ligand

Ming Dong Zhou; Shu Liang Zang; Eberhardt Herdtweck; Fritz E. Kühn

doi:10.1016/j.jorganchem.2008.05.003

A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII)-Cis-and trans-coordination of the ligand

Ming Dong Zhou
, Shu Liang Zang
, Eberhardt Herdtweck
, Fritz E. Kühn

Associate Professorship of Molecular Catalysis

Technical University of Munich
Liaoning Shihua University

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII), displaying both a cis- and a trans-arrangement of the Schiff-base ligand to the Re bound methyl group has been synthesized and described. Despite displaying some significant differences in the solid state (e.g. Re-O (Schiff base) bond distance, Re-C bond distance and several bond angles), the two configurations are indistinguishable in solution, obviously interchanging quickly.

Original language	English
Pages (from-to)	2473-2477
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	693
Issue number	15
DOIs	https://doi.org/10.1016/j.jorganchem.2008.05.003
State	Published - 15 Jul 2008

Keywords

Catalysis
Methyltrioxorhenium(VII)
Salicylidene(aniline)
Schiff base
Solid state structure

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10.1016/j.jorganchem.2008.05.003

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title = "A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII)-Cis-and trans-coordination of the ligand",

abstract = "A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII), displaying both a cis- and a trans-arrangement of the Schiff-base ligand to the Re bound methyl group has been synthesized and described. Despite displaying some significant differences in the solid state (e.g. Re-O (Schiff base) bond distance, Re-C bond distance and several bond angles), the two configurations are indistinguishable in solution, obviously interchanging quickly.",

keywords = "Catalysis, Methyltrioxorhenium(VII), Salicylidene(aniline), Schiff base, Solid state structure",

author = "Zhou, \{Ming Dong\} and Zang, \{Shu Liang\} and Eberhardt Herdtweck and K{\"u}hn, \{Fritz E.\}",

year = "2008",

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day = "15",

doi = "10.1016/j.jorganchem.2008.05.003",

language = "English",

volume = "693",

pages = "2473--2477",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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TY - JOUR

T1 - A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII)-Cis-and trans-coordination of the ligand

AU - Zhou, Ming Dong

AU - Zang, Shu Liang

AU - Herdtweck, Eberhardt

AU - Kühn, Fritz E.

PY - 2008/7/15

Y1 - 2008/7/15

N2 - A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII), displaying both a cis- and a trans-arrangement of the Schiff-base ligand to the Re bound methyl group has been synthesized and described. Despite displaying some significant differences in the solid state (e.g. Re-O (Schiff base) bond distance, Re-C bond distance and several bond angles), the two configurations are indistinguishable in solution, obviously interchanging quickly.

AB - A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII), displaying both a cis- and a trans-arrangement of the Schiff-base ligand to the Re bound methyl group has been synthesized and described. Despite displaying some significant differences in the solid state (e.g. Re-O (Schiff base) bond distance, Re-C bond distance and several bond angles), the two configurations are indistinguishable in solution, obviously interchanging quickly.

KW - Catalysis

KW - Methyltrioxorhenium(VII)

KW - Salicylidene(aniline)

KW - Schiff base

KW - Solid state structure

UR - https://www.scopus.com/pages/publications/45849091505

U2 - 10.1016/j.jorganchem.2008.05.003

DO - 10.1016/j.jorganchem.2008.05.003

M3 - Article

AN - SCOPUS:45849091505

SN - 0022-328X

VL - 693

SP - 2473

EP - 2477

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 15

ER -

A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII)-Cis-and trans-coordination of the ligand

Abstract

Keywords

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