A polymer-bound chiral template for enantioselective photochemical reactions

Stefan Breitenlechner; Thorsten Bach

doi:10.1002/anie.200802479

A polymer-bound chiral template for enantioselective photochemical reactions

Stefan Breitenlechner, Thorsten Bach

Chair of Organic Chemistry 1

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

A happy couple: A chiral complexing agent was modified with an ω-hydroxyalkyl linker and immobilized on a Wang resin and on a methoxypolyethylene glycol (MPEG 2000). The immobilized templates 1 served in an enantioselective photochemical reaction with impressive selectivity (e.r. 92:8 to 96:4) and stability over several cycles. (Figure Presented).

Original language	English
Pages (from-to)	7957-7959
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	47
Issue number	41
DOIs	https://doi.org/10.1002/anie.200802479
State	Published - 29 Sep 2008

Keywords

Cycloaddition
Enantioselectivity
Photochemistry
Polymers
Solid-phase synthesis

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10.1002/anie.200802479

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abstract = "A happy couple: A chiral complexing agent was modified with an ω-hydroxyalkyl linker and immobilized on a Wang resin and on a methoxypolyethylene glycol (MPEG 2000). The immobilized templates 1 served in an enantioselective photochemical reaction with impressive selectivity (e.r. 92:8 to 96:4) and stability over several cycles. (Figure Presented).",

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AU - Bach, Thorsten

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AB - A happy couple: A chiral complexing agent was modified with an ω-hydroxyalkyl linker and immobilized on a Wang resin and on a methoxypolyethylene glycol (MPEG 2000). The immobilized templates 1 served in an enantioselective photochemical reaction with impressive selectivity (e.r. 92:8 to 96:4) and stability over several cycles. (Figure Presented).

KW - Cycloaddition

KW - Enantioselectivity

KW - Photochemistry

KW - Polymers

KW - Solid-phase synthesis

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M3 - Article

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 41

ER -

A polymer-bound chiral template for enantioselective photochemical reactions

Abstract

Keywords

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