A polymer-bound chiral template for enantioselective photochemical reactions

Stefan Breitenlechner, Thorsten Bach

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

A happy couple: A chiral complexing agent was modified with an ω-hydroxyalkyl linker and immobilized on a Wang resin and on a methoxypolyethylene glycol (MPEG 2000). The immobilized templates 1 served in an enantioselective photochemical reaction with impressive selectivity (e.r. 92:8 to 96:4) and stability over several cycles. (Figure Presented).

Original languageEnglish
Pages (from-to)7957-7959
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume47
Issue number41
DOIs
StatePublished - 29 Sep 2008

Keywords

  • Cycloaddition
  • Enantioselectivity
  • Photochemistry
  • Polymers
  • Solid-phase synthesis

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