A palladium-catalyzed cyclization - oxidation sequence: Synthesis of bicyclo[3.1.0]hexanes and evidence for SN2 C-O bond formation

Xiaofeng Tong, Matthias Beller, Kin Tse Man

Research output: Contribution to journalArticlepeer-review

145 Scopus citations

Abstract

A novel palladium-catalyzed cyclization-oxidation sequence yielding bicyclo[3.1.0]hexanes was developed. A mechanism involving a Pd(II)/Pd(IV) cycle was proposed. An SN2 C-O bond formation from an alkyl-palladium(IV) intermediate was also suggested.

Original languageEnglish
Pages (from-to)4906-4907
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number16
DOIs
StatePublished - 25 Apr 2007
Externally publishedYes

Fingerprint

Dive into the research topics of 'A palladium-catalyzed cyclization - oxidation sequence: Synthesis of bicyclo[3.1.0]hexanes and evidence for SN2 C-O bond formation'. Together they form a unique fingerprint.

Cite this