A Novel Ylidic Organophosphorus Ligand

Hubert Schmidbaur; Ulrich Deschler; Beatrix Milewski‐Mahrla

doi:10.1002/anie.198105861

A Novel Ylidic Organophosphorus Ligand

Hubert Schmidbaur
, Ulrich Deschler
, Beatrix Milewski‐Mahrla

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A particularly effective combination of the donor properties of phosphanes and phosphorus ylides has been achieved in the chelate system characterized by the resonance structures A and B. Reaction with [(CH₃)₃P]₂NiCl₂ leads via alkali metal intermediates to the lemon‐yellow, air‐ and moisture‐sensitive complex 1. (Figure Presented.)

Original language	English
Pages (from-to)	586-588
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	20
Issue number	6-7
DOIs	https://doi.org/10.1002/anie.198105861
State	Published - 1981

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@article{8d83d0c4ce1a4eb5bf73cedc1327ddcc,

title = "A Novel Ylidic Organophosphorus Ligand",

abstract = "A particularly effective combination of the donor properties of phosphanes and phosphorus ylides has been achieved in the chelate system characterized by the resonance structures A and B. Reaction with [(CH3)3P]2NiCl2 leads via alkali metal intermediates to the lemon‐yellow, air‐ and moisture‐sensitive complex 1. (Figure Presented.)",

author = "Hubert Schmidbaur and Ulrich Deschler and Beatrix Milewski‐Mahrla",

year = "1981",

doi = "10.1002/anie.198105861",

language = "English",

volume = "20",

pages = "586--588",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Ltd",

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T1 - A Novel Ylidic Organophosphorus Ligand

AU - Schmidbaur, Hubert

AU - Deschler, Ulrich

AU - Milewski‐Mahrla, Beatrix

PY - 1981

Y1 - 1981

N2 - A particularly effective combination of the donor properties of phosphanes and phosphorus ylides has been achieved in the chelate system characterized by the resonance structures A and B. Reaction with [(CH3)3P]2NiCl2 leads via alkali metal intermediates to the lemon‐yellow, air‐ and moisture‐sensitive complex 1. (Figure Presented.)

AB - A particularly effective combination of the donor properties of phosphanes and phosphorus ylides has been achieved in the chelate system characterized by the resonance structures A and B. Reaction with [(CH3)3P]2NiCl2 leads via alkali metal intermediates to the lemon‐yellow, air‐ and moisture‐sensitive complex 1. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84985521809

U2 - 10.1002/anie.198105861

DO - 10.1002/anie.198105861

M3 - Article

AN - SCOPUS:84985521809

SN - 0570-0833

VL - 20

SP - 586

EP - 588

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 6-7

ER -

A Novel Ylidic Organophosphorus Ligand

Abstract

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