A novel As42+ structural unit with diphosphinomethanide bridging ligands from the reaction of AsCl3 with Li[C(PMe2)2(SiMe3)]

Hans H. Karsch; Annette Schier

doi:10.1039/C39940002703

A novel As₄²⁺ structural unit with diphosphinomethanide bridging ligands from the reaction of AsCl₃ with Li[C(PMe₂)₂(SiMe₃)]

Hans H. Karsch, Annette Schier

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Technical University of Munich

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Abstract

Two As₂[C(PMe₂)₂(SiMe₃)] five membered ring units are linked via an As-As bond and thus form an As ₄²⁺ chain in a compound obtained from a redox reaction between AsCl₃ and Li[C(PMe₂)₂(SiMe ₃)].

Original language	English
Pages (from-to)	2703-2704
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/C39940002703
State	Published - 1994

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@article{6edd93a74cff4d9bbc2b6299c95c0ebe,

title = "A novel As42+ structural unit with diphosphinomethanide bridging ligands from the reaction of AsCl3 with Li[C(PMe2)2(SiMe3)]",

abstract = "Two As2[C(PMe2)2(SiMe3)] five membered ring units are linked via an As-As bond and thus form an As 42+ chain in a compound obtained from a redox reaction between AsCl3 and Li[C(PMe2)2(SiMe 3)].",

author = "Karsch, {Hans H.} and Annette Schier",

year = "1994",

doi = "10.1039/C39940002703",

language = "English",

pages = "2703--2704",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "23",

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TY - JOUR

T1 - A novel As42+ structural unit with diphosphinomethanide bridging ligands from the reaction of AsCl3 with Li[C(PMe2)2(SiMe3)]

AU - Karsch, Hans H.

AU - Schier, Annette

PY - 1994

Y1 - 1994

N2 - Two As2[C(PMe2)2(SiMe3)] five membered ring units are linked via an As-As bond and thus form an As 42+ chain in a compound obtained from a redox reaction between AsCl3 and Li[C(PMe2)2(SiMe 3)].

AB - Two As2[C(PMe2)2(SiMe3)] five membered ring units are linked via an As-As bond and thus form an As 42+ chain in a compound obtained from a redox reaction between AsCl3 and Li[C(PMe2)2(SiMe 3)].

UR - http://www.scopus.com/inward/record.url?scp=37049066537&partnerID=8YFLogxK

U2 - 10.1039/C39940002703

DO - 10.1039/C39940002703

M3 - Article

AN - SCOPUS:37049066537

SN - 0022-4936

SP - 2703

EP - 2704

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 23

ER -

A novel As₄²⁺ structural unit with diphosphinomethanide bridging ligands from the reaction of AsCl₃ with Li[C(PMe₂)₂(SiMe₃)]

Abstract

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