A new palladium(II) complex of a functionalized N-heterocyclic carbene: Synthesis, characterization and application in Suzuki-Miyaura cross-coupling reactions

Claudia S. Linninger, Eberhardt Herdtweck, Stephan D. Hoffmann, Wolfgang A. Herrmann, Fritz E. Kühn

Research output: Contribution to journalArticlepeer-review

40 Scopus citations

Abstract

trans-[PdBr2(NHC)Im] was prepared by reacting the corresponding imidazolium (Im) salt with palladium(II) acetate in dimethylsulfoxide in an in-situ reaction without generating a free carbene. Both the salt and the complex were characterized spectroscopically and by X-ray structure analysis. The complex was tested in homogeneous Suzuki-Miyaura cross-coupling reactions.

Original languageEnglish
Pages (from-to)192-197
Number of pages6
JournalJournal of Molecular Structure
Volume890
Issue number1-3
DOIs
StatePublished - 12 Nov 2008

Keywords

  • Imidazolium salt
  • N-heterocyclic carbene
  • Palladium
  • Suzuki-Miyaura cross-coupling

Fingerprint

Dive into the research topics of 'A new palladium(II) complex of a functionalized N-heterocyclic carbene: Synthesis, characterization and application in Suzuki-Miyaura cross-coupling reactions'. Together they form a unique fingerprint.

Cite this