A neutral crystalline imino-substituted silyl radical

Fiona J. Kiefer; Arseni Kostenko; Richard Holzner; Shigeyoshi Inoue

doi:10.1039/d4cc02167c

A neutral crystalline imino-substituted silyl radical

Fiona J. Kiefer, Arseni Kostenko, Richard Holzner, Shigeyoshi Inoue

Associate Professorship of Silicon Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (I^tBuN-SiBr₃) with NaSi^tBu₂Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.

Original language	English
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/d4cc02167c
State	Accepted/In press - 2024

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10.1039/d4cc02167c

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title = "A neutral crystalline imino-substituted silyl radical",

abstract = "The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.",

author = "Kiefer, {Fiona J.} and Arseni Kostenko and Richard Holzner and Shigeyoshi Inoue",

note = "Publisher Copyright: {\textcopyright} 2024 The Royal Society of Chemistry.",

year = "2024",

doi = "10.1039/d4cc02167c",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - A neutral crystalline imino-substituted silyl radical

AU - Kiefer, Fiona J.

AU - Kostenko, Arseni

AU - Holzner, Richard

AU - Inoue, Shigeyoshi

PY - 2024

Y1 - 2024

N2 - The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.

AB - The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.

UR - http://www.scopus.com/inward/record.url?scp=85199534306&partnerID=8YFLogxK

U2 - 10.1039/d4cc02167c

DO - 10.1039/d4cc02167c

M3 - Article

C2 - 39045633

AN - SCOPUS:85199534306

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

A neutral crystalline imino-substituted silyl radical

Abstract

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