TY - JOUR
T1 - A light, chondritic xenolith in the Murchison (CM) chondrite – Formation by fluid-assisted percolation during metasomatism?
AU - Kerraouch, Imene
AU - Ebert, Samuel
AU - Patzek, Markus
AU - Bischoff, Addi
AU - Zolensky, Michael E.
AU - Pack, Andreas
AU - Schmitt-Kopplin, Philippe
AU - Belhai, Djelloul
AU - Bendaoud, Abderrahmane
AU - Le, Loan
N1 - Publisher Copyright:
© 2019 Elsevier GmbH
PY - 2019/12
Y1 - 2019/12
N2 - The main mineralogical characteristics of a large light-colored clast within the Murchison CM breccia are discussed in detail including data on the mineralogy, bulk chemistry, organics, and oxygen isotopes. Petrographic study shows that the white clast consists of two areas with different granoblastic textures: (1) a coarse-grained (average grain size: ∼200 μm) and (2) a fine-grained lithology (average grain-size: ∼20 μm). The Fa-content of olivine in the clast is the same as Fa within olivine from Rumuruti (R) chondrites (Fa: ∼38 mol%); however, the concentrations of the elements Ni and Ca in olivine are significantly different. The fragment also contains Ca-rich pyroxene, ∼An30-38-plagioclase/maskelynite, Cr-rich spinel, several sulfide phases, a nepheline-normative glass, and traces of merrillite and metal. The occurrence of maskelynite and nepheline-normative amorphous phase in restricted areas of the well-recrystallized rock may indicate remarkable P-T-excursions during shock metamorphism. The O-isotope composition of the clast falls below the terrestrial fractionation line (TFL), lying in the field of CM chondrites and is significantly different from data for bulk R chondrites. The study of the soluble organic matter revealed a highly-oxidized carbon chemistry and organomagnesium compounds reflecting high temperature and pressure processes.
AB - The main mineralogical characteristics of a large light-colored clast within the Murchison CM breccia are discussed in detail including data on the mineralogy, bulk chemistry, organics, and oxygen isotopes. Petrographic study shows that the white clast consists of two areas with different granoblastic textures: (1) a coarse-grained (average grain size: ∼200 μm) and (2) a fine-grained lithology (average grain-size: ∼20 μm). The Fa-content of olivine in the clast is the same as Fa within olivine from Rumuruti (R) chondrites (Fa: ∼38 mol%); however, the concentrations of the elements Ni and Ca in olivine are significantly different. The fragment also contains Ca-rich pyroxene, ∼An30-38-plagioclase/maskelynite, Cr-rich spinel, several sulfide phases, a nepheline-normative glass, and traces of merrillite and metal. The occurrence of maskelynite and nepheline-normative amorphous phase in restricted areas of the well-recrystallized rock may indicate remarkable P-T-excursions during shock metamorphism. The O-isotope composition of the clast falls below the terrestrial fractionation line (TFL), lying in the field of CM chondrites and is significantly different from data for bulk R chondrites. The study of the soluble organic matter revealed a highly-oxidized carbon chemistry and organomagnesium compounds reflecting high temperature and pressure processes.
KW - Brecciation
KW - Carbonaceous chondrite
KW - Metamorphism
KW - Murchison
KW - Percolation
KW - White clast
UR - http://www.scopus.com/inward/record.url?scp=85067660257&partnerID=8YFLogxK
U2 - 10.1016/j.chemer.2019.06.002
DO - 10.1016/j.chemer.2019.06.002
M3 - Article
AN - SCOPUS:85067660257
SN - 0009-2819
VL - 79
JO - Chemie der Erde
JF - Chemie der Erde
IS - 4
M1 - 125518
ER -