A general and practical Ni-catalyzed C-H perfluoroalkylation of (hetero)arenes

Shaoke Zhang, Nicolas Rotta-Loria, Florian Weniger, Jabor Rabeah, Helfried Neumann, Christoph Taeschler, Matthias Beller

Research output: Contribution to journalArticlepeer-review

21 Scopus citations

Abstract

A direct perfluoroalkylation of (hetero)arenes using the air- and moisture-stable complex (dppf)Ni(o-tol)Cl was developed (23 examples). The novel procedure allows for the synthesis of various fluorinated products and tolerates sensitive functional groups including aldehydes, free amino groups and several heterocycles.

Original languageEnglish
Pages (from-to)6723-6726
Number of pages4
JournalChemical Communications
Volume55
Issue number47
DOIs
StatePublished - 2019
Externally publishedYes

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