A Dramatic Effect of Aryloxo Ligands on the Titanium-Catalyzed Hydroamination of Alkynes

Vivek Khedkar, Annegret Tillack, Matthias Beller

Research output: Contribution to journalArticlepeer-review

87 Scopus citations

Abstract

(Equation Presented) The aryloxotitanium complex 1 is a highly chemo- and regioselective catalyst for intermolecular hydroamination of terminal alkynes. Branched imines are obtained in good to excellent yield (up to 99%) with various primary aromatic and aliphatic amines.

Original languageEnglish
Pages (from-to)4767-4770
Number of pages4
JournalOrganic Letters
Volume5
Issue number25
DOIs
StatePublished - 11 Dec 2003
Externally publishedYes

Fingerprint

Dive into the research topics of 'A Dramatic Effect of Aryloxo Ligands on the Titanium-Catalyzed Hydroamination of Alkynes'. Together they form a unique fingerprint.

Cite this