A dichloropalladium(II) complex with a mixed donor bidentate ligand: Dichloro[2-(diphenylphosphino)-1-(methylthio)ethane-P,S]palladium(II)

Adnan S. Abu-Surrah; Kristian Lappalainen; Martti Klinga; Markku Leskelä; Hamdallah A. Hodali; Bernhard Rieger

doi:10.1107/S0108270198012773

A dichloropalladium(II) complex with a mixed donor bidentate ligand: Dichloro[2-(diphenylphosphino)-1-(methylthio)ethane-P,S]palladium(II)

Adnan S. Abu-Surrah
, Kristian Lappalainen
, Martti Klinga
, Markku Leskelä
, Hamdallah A. Hodali
, Bernhard Rieger

University of Ulm
University of Helsinki
University of Jordan

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The title compound, [PdCl₂(C₁₅H₁₇PS)], was prepared by the reaction of cis-dichlorobis(benzonitrile)-palladium(II) with the ligand 1-(thiomethyl)-2-(diphenylphosphino)ethane in acetone. The crystal structure of the resulting palladium(II) complex has been determined. The length of the Pd-Cl bonds is consistent with the trans-influence order: P > S.

Original language	English
Pages (from-to)	188-190
Number of pages	3
Journal	Acta Crystallographica Section C
Volume	55
Issue number	2
DOIs	https://doi.org/10.1107/S0108270198012773
State	Published - 15 Feb 1999
Externally published	Yes

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title = "A dichloropalladium(II) complex with a mixed donor bidentate ligand: Dichloro[2-(diphenylphosphino)-1-(methylthio)ethane-P,S]palladium(II)",

abstract = "The title compound, [PdCl2(C15H17PS)], was prepared by the reaction of cis-dichlorobis(benzonitrile)-palladium(II) with the ligand 1-(thiomethyl)-2-(diphenylphosphino)ethane in acetone. The crystal structure of the resulting palladium(II) complex has been determined. The length of the Pd-Cl bonds is consistent with the trans-influence order: P > S.",

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year = "1999",

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doi = "10.1107/S0108270198012773",

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T1 - A dichloropalladium(II) complex with a mixed donor bidentate ligand

T2 - Dichloro[2-(diphenylphosphino)-1-(methylthio)ethane-P,S]palladium(II)

AU - Abu-Surrah, Adnan S.

AU - Lappalainen, Kristian

AU - Klinga, Martti

AU - Leskelä, Markku

AU - Hodali, Hamdallah A.

AU - Rieger, Bernhard

PY - 1999/2/15

Y1 - 1999/2/15

N2 - The title compound, [PdCl2(C15H17PS)], was prepared by the reaction of cis-dichlorobis(benzonitrile)-palladium(II) with the ligand 1-(thiomethyl)-2-(diphenylphosphino)ethane in acetone. The crystal structure of the resulting palladium(II) complex has been determined. The length of the Pd-Cl bonds is consistent with the trans-influence order: P > S.

AB - The title compound, [PdCl2(C15H17PS)], was prepared by the reaction of cis-dichlorobis(benzonitrile)-palladium(II) with the ligand 1-(thiomethyl)-2-(diphenylphosphino)ethane in acetone. The crystal structure of the resulting palladium(II) complex has been determined. The length of the Pd-Cl bonds is consistent with the trans-influence order: P > S.

UR - https://www.scopus.com/pages/publications/0001448550

U2 - 10.1107/S0108270198012773

DO - 10.1107/S0108270198012773

M3 - Article

AN - SCOPUS:0001448550

SN - 0108-2701

VL - 55

SP - 188

EP - 190

JO - Acta Crystallographica Section C

JF - Acta Crystallographica Section C

IS - 2

ER -

A dichloropalladium(II) complex with a mixed donor bidentate ligand: Dichloro[2-(diphenylphosphino)-1-(methylthio)ethane-P,S]palladium(II)

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