A dichloropalladium(II) complex with a mixed donor bidentate ligand: Dichloro[2-(diphenylphosphino)-1-(methylthio)ethane-P,S]palladium(II)

Adnan S. Abu-Surrah, Kristian Lappalainen, Martti Klinga, Markku Leskelä, Hamdallah A. Hodali, Bernhard Rieger

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Abstract

The title compound, [PdCl2(C15H17PS)], was prepared by the reaction of cis-dichlorobis(benzonitrile)-palladium(II) with the ligand 1-(thiomethyl)-2-(diphenylphosphino)ethane in acetone. The crystal structure of the resulting palladium(II) complex has been determined. The length of the Pd-Cl bonds is consistent with the trans-influence order: P > S.

Original languageEnglish
Pages (from-to)188-190
Number of pages3
JournalActa Crystallographica Section C
Volume55
Issue number2
DOIs
StatePublished - 15 Feb 1999
Externally publishedYes

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