A cyclic germadicarbene ("germylone") from germyliumylidene

Yun Xiong, Shenglai Yao, Gengwen Tan, Shigeyoshi Inoue, Matthias Driess

Research output: Contribution to journalArticlepeer-review

189 Scopus citations

Abstract

By employing the chelate dicarbene 1, the new chlorogermyliumylidene complex 2 could be synthesized and isolated in 95% yield. Dechlorination of 2 with sodium naphthalenide furnishes the unique cyclic germadicarbene 3 which could be isolated in 45% yield. Compound 3 is the first isolable Ge(0) complex with a single germanium atom stabilized by a dicarbene. Its molecular structure is in accordance with DFT calculations which underline the peculiar electronic structure of 3 with two lone pairs of electrons at the Ge atom.

Original languageEnglish
Pages (from-to)5004-5007
Number of pages4
JournalJournal of the American Chemical Society
Volume135
Issue number13
DOIs
StatePublished - 3 Apr 2013
Externally publishedYes

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