A comparative study of polychlorinated alkanes as standards for the determination of C10-C13 polychlorinated paraffines in fish samples

Mehmet Coelhan; Majlinda Saraci; Harun Parlar

doi:10.1016/S0045-6535(99)00444-0

A comparative study of polychlorinated alkanes as standards for the determination of C10-C13 polychlorinated paraffines in fish samples

Mehmet Coelhan, Majlinda Saraci, Harun Parlar

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

Fish samples of different origins have been analysed with short column gas chromatography-electron capture negative ion/mass spectrometry (SCGC/ECNI-MS). The influence of standards composed from different polychlorinated alkanes on the quantification of short chain polychlorinated paraffines (CP) was studied. Concentration values varied very differently with the response of the standards depending on their chlorination degree. The results show, that technical CP products should not be used as standard in most cases, because the composition of polychlorinated alkanes in fish is different from sample to sample.

Original language	English
Pages (from-to)	685-689
Number of pages	5
Journal	Chemosphere
Volume	40
Issue number	6
DOIs	https://doi.org/10.1016/S0045-6535(99)00444-0
State	Published - Mar 2000

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abstract = "Fish samples of different origins have been analysed with short column gas chromatography-electron capture negative ion/mass spectrometry (SCGC/ECNI-MS). The influence of standards composed from different polychlorinated alkanes on the quantification of short chain polychlorinated paraffines (CP) was studied. Concentration values varied very differently with the response of the standards depending on their chlorination degree. The results show, that technical CP products should not be used as standard in most cases, because the composition of polychlorinated alkanes in fish is different from sample to sample.",

author = "Mehmet Coelhan and Majlinda Saraci and Harun Parlar",

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AB - Fish samples of different origins have been analysed with short column gas chromatography-electron capture negative ion/mass spectrometry (SCGC/ECNI-MS). The influence of standards composed from different polychlorinated alkanes on the quantification of short chain polychlorinated paraffines (CP) was studied. Concentration values varied very differently with the response of the standards depending on their chlorination degree. The results show, that technical CP products should not be used as standard in most cases, because the composition of polychlorinated alkanes in fish is different from sample to sample.

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A comparative study of polychlorinated alkanes as standards for the determination of C10-C13 polychlorinated paraffines in fish samples

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