A combinatorial coordination-modulated approach to all-hydrocarbon-ligated intermetallic clusters

Patricia Heiß; Julius Hornung; Christian Gemel; Roland A. Fischer

doi:10.1039/d2cc00396a

A combinatorial coordination-modulated approach to all-hydrocarbon-ligated intermetallic clusters

Patricia Heiß
, Julius Hornung
, Christian Gemel
, Roland A. Fischer

Chair of Inorganic and Organometallic Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The formation of Hume-Rothery-inspired intermetallic and all-hydrocarbon-ligated Ni/E clusters (E = Al, Ga) is studied. A library of organo-metallic complexes and small clusters is obtained when [Ni(cod)₂] is treated with ECp* in the presence of 3-hexyne (hex). While the alkyne reversibly coordinates side-on to the Ni/Ga species, it dimerizes at the Ni/Al species.

Original language	English
Pages (from-to)	4332-4335
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	27
DOIs	https://doi.org/10.1039/d2cc00396a
State	Published - 8 Mar 2022

Access to Document

10.1039/d2cc00396a

Cite this

@article{941d7aa324964ba18a9d77c6865d7d1d,

title = "A combinatorial coordination-modulated approach to all-hydrocarbon-ligated intermetallic clusters",

abstract = "The formation of Hume-Rothery-inspired intermetallic and all-hydrocarbon-ligated Ni/E clusters (E = Al, Ga) is studied. A library of organo-metallic complexes and small clusters is obtained when [Ni(cod)2] is treated with ECp* in the presence of 3-hexyne (hex). While the alkyne reversibly coordinates side-on to the Ni/Ga species, it dimerizes at the Ni/Al species.",

author = "Patricia Hei{\ss} and Julius Hornung and Christian Gemel and Fischer, \{Roland A.\}",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry",

year = "2022",

month = mar,

day = "8",

doi = "10.1039/d2cc00396a",

language = "English",

volume = "58",

pages = "4332--4335",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "27",

}

TY - JOUR

T1 - A combinatorial coordination-modulated approach to all-hydrocarbon-ligated intermetallic clusters

AU - Heiß, Patricia

AU - Hornung, Julius

AU - Gemel, Christian

AU - Fischer, Roland A.

PY - 2022/3/8

Y1 - 2022/3/8

N2 - The formation of Hume-Rothery-inspired intermetallic and all-hydrocarbon-ligated Ni/E clusters (E = Al, Ga) is studied. A library of organo-metallic complexes and small clusters is obtained when [Ni(cod)2] is treated with ECp* in the presence of 3-hexyne (hex). While the alkyne reversibly coordinates side-on to the Ni/Ga species, it dimerizes at the Ni/Al species.

AB - The formation of Hume-Rothery-inspired intermetallic and all-hydrocarbon-ligated Ni/E clusters (E = Al, Ga) is studied. A library of organo-metallic complexes and small clusters is obtained when [Ni(cod)2] is treated with ECp* in the presence of 3-hexyne (hex). While the alkyne reversibly coordinates side-on to the Ni/Ga species, it dimerizes at the Ni/Al species.

UR - https://www.scopus.com/pages/publications/85127550710

U2 - 10.1039/d2cc00396a

DO - 10.1039/d2cc00396a

M3 - Article

C2 - 35290423

AN - SCOPUS:85127550710

SN - 1359-7345

VL - 58

SP - 4332

EP - 4335

JO - Chemical Communications

JF - Chemical Communications

IS - 27

ER -

A combinatorial coordination-modulated approach to all-hydrocarbon-ligated intermetallic clusters

Abstract

Access to Document

Other files and links

Fingerprint

Cite this