A combinatorial coordination-modulated approach to all-hydrocarbon-ligated intermetallic clusters

Patricia Heiß; Julius Hornung; Christian Gemel; Roland A. Fischer

doi:10.1039/d2cc00396a

A combinatorial coordination-modulated approach to all-hydrocarbon-ligated intermetallic clusters

Patricia Heiß, Julius Hornung, Christian Gemel, Roland A. Fischer

Chair of Inorganic and Organometallic Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The formation of Hume-Rothery-inspired intermetallic and all-hydrocarbon-ligated Ni/E clusters (E = Al, Ga) is studied. A library of organo-metallic complexes and small clusters is obtained when [Ni(cod)₂] is treated with ECp* in the presence of 3-hexyne (hex). While the alkyne reversibly coordinates side-on to the Ni/Ga species, it dimerizes at the Ni/Al species.

Original language	English
Pages (from-to)	4332-4335
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	27
DOIs	https://doi.org/10.1039/d2cc00396a
State	Published - 8 Mar 2022

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abstract = "The formation of Hume-Rothery-inspired intermetallic and all-hydrocarbon-ligated Ni/E clusters (E = Al, Ga) is studied. A library of organo-metallic complexes and small clusters is obtained when [Ni(cod)2] is treated with ECp* in the presence of 3-hexyne (hex). While the alkyne reversibly coordinates side-on to the Ni/Ga species, it dimerizes at the Ni/Al species.",

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N2 - The formation of Hume-Rothery-inspired intermetallic and all-hydrocarbon-ligated Ni/E clusters (E = Al, Ga) is studied. A library of organo-metallic complexes and small clusters is obtained when [Ni(cod)2] is treated with ECp* in the presence of 3-hexyne (hex). While the alkyne reversibly coordinates side-on to the Ni/Ga species, it dimerizes at the Ni/Al species.

AB - The formation of Hume-Rothery-inspired intermetallic and all-hydrocarbon-ligated Ni/E clusters (E = Al, Ga) is studied. A library of organo-metallic complexes and small clusters is obtained when [Ni(cod)2] is treated with ECp* in the presence of 3-hexyne (hex). While the alkyne reversibly coordinates side-on to the Ni/Ga species, it dimerizes at the Ni/Al species.

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ER -

A combinatorial coordination-modulated approach to all-hydrocarbon-ligated intermetallic clusters

Abstract

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