A cheap, efficient, and environmentally benign synthesis of the versatile catalyst methyltrioxorhenium (MTO)

Wolfgang A. Herrmann; Alexandra M.J. Rost; Josef K.M. Mitterpleininger; Normen Szesni; Stefanie Sturm; Richard W. Fischer; Fritz E. Kühn

doi:10.1002/anie.200703017

A cheap, efficient, and environmentally benign synthesis of the versatile catalyst methyltrioxorhenium (MTO)

Wolfgang A. Herrmann, Alexandra M.J. Rost, Josef K.M. Mitterpleininger, Normen Szesni, Stefanie Sturm, Richard W. Fischer, Fritz E. Kühn

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

Avoiding toxic starting materials such as (CH₃)₄Sn, a cheap, environmentally benign high-yield synthesis has been developed for the multitalented catalyst methyltrioxorhenium(VII) (MTO; see picture: black C, white H, blue Re, red O). This novel approach is applicable on a large scale and for several derivatives of MTO, such as ethyltrioxorhenium(VII). (Figure Presented)

Original language	English
Pages (from-to)	7301-7303
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	46
Issue number	38
DOIs	https://doi.org/10.1002/anie.200703017
State	Published - 2007

Keywords

Alkylation
Catalysts
Rhenium
Synthetic methods
Zinc

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abstract = "Avoiding toxic starting materials such as (CH3)4Sn, a cheap, environmentally benign high-yield synthesis has been developed for the multitalented catalyst methyltrioxorhenium(VII) (MTO; see picture: black C, white H, blue Re, red O). This novel approach is applicable on a large scale and for several derivatives of MTO, such as ethyltrioxorhenium(VII). (Figure Presented)",

keywords = "Alkylation, Catalysts, Rhenium, Synthetic methods, Zinc",

author = "Herrmann, {Wolfgang A.} and Rost, {Alexandra M.J.} and Mitterpleininger, {Josef K.M.} and Normen Szesni and Stefanie Sturm and Fischer, {Richard W.} and K{\"u}hn, {Fritz E.}",

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T1 - A cheap, efficient, and environmentally benign synthesis of the versatile catalyst methyltrioxorhenium (MTO)

AU - Herrmann, Wolfgang A.

AU - Rost, Alexandra M.J.

AU - Mitterpleininger, Josef K.M.

AU - Szesni, Normen

AU - Sturm, Stefanie

AU - Fischer, Richard W.

AU - Kühn, Fritz E.

PY - 2007

Y1 - 2007

N2 - Avoiding toxic starting materials such as (CH3)4Sn, a cheap, environmentally benign high-yield synthesis has been developed for the multitalented catalyst methyltrioxorhenium(VII) (MTO; see picture: black C, white H, blue Re, red O). This novel approach is applicable on a large scale and for several derivatives of MTO, such as ethyltrioxorhenium(VII). (Figure Presented)

AB - Avoiding toxic starting materials such as (CH3)4Sn, a cheap, environmentally benign high-yield synthesis has been developed for the multitalented catalyst methyltrioxorhenium(VII) (MTO; see picture: black C, white H, blue Re, red O). This novel approach is applicable on a large scale and for several derivatives of MTO, such as ethyltrioxorhenium(VII). (Figure Presented)

KW - Alkylation

KW - Catalysts

KW - Rhenium

KW - Synthetic methods

KW - Zinc

UR - http://www.scopus.com/inward/record.url?scp=34948823458&partnerID=8YFLogxK

U2 - 10.1002/anie.200703017

DO - 10.1002/anie.200703017

M3 - Article

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SN - 1433-7851

VL - 46

SP - 7301

EP - 7303

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 38

ER -

A cheap, efficient, and environmentally benign synthesis of the versatile catalyst methyltrioxorhenium (MTO)

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Keywords

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