A 2‐Phosphonio‐Substituted 1‐Phospha‐1‐alkene: Resonance between PIII Alkene and PV Ylide

Hans H. Karsch; Hans‐Ulrich ‐U Reisacher; Gerhard Müller

doi:10.1002/anie.198604541

A 2‐Phosphonio‐Substituted 1‐Phospha‐1‐alkene: Resonance between P^III Alkene and P^V Ylide

Hans H. Karsch
, Hans‐Ulrich ‐U Reisacher
, Gerhard Müller

Natural Sciences

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

How realistic is a resonance of the type A ↔ B ↔ C? This question could be answered from the NMR spectroscopic data of 1, the first representative of the 2‐phosphonio‐substituted 1‐phospha‐1‐alkenes. A considerable amount of the resonance structures B and C was found in the actual structure of 1 (R = 2,4,6‐tBu₃C₆H₂). (Figure Presented.)

Original language	English
Pages (from-to)	454-455
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	25
Issue number	5
DOIs	https://doi.org/10.1002/anie.198604541
State	Published - May 1986

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abstract = "How realistic is a resonance of the type A ↔ B ↔ C? This question could be answered from the NMR spectroscopic data of 1, the first representative of the 2‐phosphonio‐substituted 1‐phospha‐1‐alkenes. A considerable amount of the resonance structures B and C was found in the actual structure of 1 (R = 2,4,6‐tBu3C6H2). (Figure Presented.)",

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AU - Müller, Gerhard

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N2 - How realistic is a resonance of the type A ↔ B ↔ C? This question could be answered from the NMR spectroscopic data of 1, the first representative of the 2‐phosphonio‐substituted 1‐phospha‐1‐alkenes. A considerable amount of the resonance structures B and C was found in the actual structure of 1 (R = 2,4,6‐tBu3C6H2). (Figure Presented.)

AB - How realistic is a resonance of the type A ↔ B ↔ C? This question could be answered from the NMR spectroscopic data of 1, the first representative of the 2‐phosphonio‐substituted 1‐phospha‐1‐alkenes. A considerable amount of the resonance structures B and C was found in the actual structure of 1 (R = 2,4,6‐tBu3C6H2). (Figure Presented.)

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ER -

A 2‐Phosphonio‐Substituted 1‐Phospha‐1‐alkene: Resonance between P^III Alkene and P^V Ylide

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