A 2‐Phosphonio‐Substituted 1‐Phospha‐1‐alkene: Resonance between PIII Alkene and PV Ylide

Hans H. Karsch, Hans‐Ulrich ‐U Reisacher, Gerhard Müller

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Abstract

How realistic is a resonance of the type A ↔ B ↔ C? This question could be answered from the NMR spectroscopic data of 1, the first representative of the 2‐phosphonio‐substituted 1‐phospha‐1‐alkenes. A considerable amount of the resonance structures B and C was found in the actual structure of 1 (R = 2,4,6‐tBu3C6H2). (Figure Presented.)

Original languageEnglish
Pages (from-to)454-455
Number of pages2
JournalAngewandte Chemie International Edition in English
Volume25
Issue number5
DOIs
StatePublished - May 1986

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