TY - JOUR
T1 - 50 Years of Passion for Organometallic Chemistry
AU - Herrmann, Wolfgang A.
N1 - Publisher Copyright:
© 2023
PY - 2023/11/1
Y1 - 2023/11/1
N2 - During a 50 years history of Organometallic Chemistry, the author - a former Regional Editor of the Journal of Organometallic Chemistry - and his Regensburg, Frankfurt, and Munich research groups contribuited to the shaping and progress of ths field which became more and more interdisciplinary ever since. Thus, akey discovery was the power and verstility of N-heterocyclic carbenes as highly activating and versatile novel catalysts ligands in various carbon-carbon bond-forming reactions, particularly olefin metathesis and Heck-type reactions. Other disseminating research contributions cover metal-metal multiple bonds, dimetallacyclopropanes, orgaometal oxides, water-soluble catalysts for the industrial hydroformylation, and metal alkoxides including organolanthanoids for CVD-processes.
AB - During a 50 years history of Organometallic Chemistry, the author - a former Regional Editor of the Journal of Organometallic Chemistry - and his Regensburg, Frankfurt, and Munich research groups contribuited to the shaping and progress of ths field which became more and more interdisciplinary ever since. Thus, akey discovery was the power and verstility of N-heterocyclic carbenes as highly activating and versatile novel catalysts ligands in various carbon-carbon bond-forming reactions, particularly olefin metathesis and Heck-type reactions. Other disseminating research contributions cover metal-metal multiple bonds, dimetallacyclopropanes, orgaometal oxides, water-soluble catalysts for the industrial hydroformylation, and metal alkoxides including organolanthanoids for CVD-processes.
KW - Dimetallacyclopropanes
KW - High and low oxidation states
KW - Metal-metal multiple bonds
KW - N-Heterocyclic carbenes
KW - Organometal oxides
KW - Organometallic catalysis
KW - Structure
KW - Synthesis
KW - Theory
UR - http://www.scopus.com/inward/record.url?scp=85165609629&partnerID=8YFLogxK
U2 - 10.1016/j.jorganchem.2023.122815
DO - 10.1016/j.jorganchem.2023.122815
M3 - Review article
AN - SCOPUS:85165609629
SN - 0022-328X
VL - 1000
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
M1 - 122815
ER -