TY - JOUR
T1 - 4‐Hydroxylation of Isoxazolines; Synthesis of rac‐Phytosphingosine (ribo‐2‐Amino‐1,3,4‐octadecanetriol)
AU - Schwab, Wilfried
AU - Jäger, Volker
PY - 1981
Y1 - 1981
N2 - The shortest and most effective phytosphingosine synthesis so far was achieved after a concept, according to which various amine sugars can be easily “assembled”. The two decisive steps in the preparation of the title compound 3, which proceed highly stereoselectively, are the hydroxylation of the isoxazoline 1 and the LiAlH4‐reduction of 2. (Figure Presented.)
AB - The shortest and most effective phytosphingosine synthesis so far was achieved after a concept, according to which various amine sugars can be easily “assembled”. The two decisive steps in the preparation of the title compound 3, which proceed highly stereoselectively, are the hydroxylation of the isoxazoline 1 and the LiAlH4‐reduction of 2. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=84985545859&partnerID=8YFLogxK
U2 - 10.1002/anie.198106031
DO - 10.1002/anie.198106031
M3 - Article
AN - SCOPUS:84985545859
SN - 0570-0833
VL - 20
SP - 603
EP - 605
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 6-7
ER -