3-Acetoxyquinuclidine as Catalyst in Electron Donor-Acceptor Complex-Mediated Reactions Triggered by Visible Light

Irene Bosque; Thorsten Bach

doi:10.1021/acscatal.9b01039

3-Acetoxyquinuclidine as Catalyst in Electron Donor-Acceptor Complex-Mediated Reactions Triggered by Visible Light

Irene Bosque, Thorsten Bach

Chair of Organic Chemistry 1

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

107 Scopus citations

Abstract

3-Acetoxyquinuclidine was found to act as a catalytic electron donor species in a variety of electron donor-acceptor complex-mediated reactions. Only substoichiometric amounts (10-25 mol %) were needed to trigger the desired reaction. The outcome could be tuned by selecting the nature of the formed radical to perform amino- and hydro-decarboxylation, dimerization, and cyclization reactions. Importantly, no external additives were needed in this reaction.

Original language	English
Pages (from-to)	9103-9109
Number of pages	7
Journal	ACS Catalysis
Volume	9
Issue number	10
DOIs	https://doi.org/10.1021/acscatal.9b01039
State	Published - 4 Oct 2019

Keywords

3-acetoxyquinuclidine
electron donor-acceptor complex
homogeneous catalysis
photochemistry
tetrachlorophthalimide

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10.1021/acscatal.9b01039

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title = "3-Acetoxyquinuclidine as Catalyst in Electron Donor-Acceptor Complex-Mediated Reactions Triggered by Visible Light",

abstract = "3-Acetoxyquinuclidine was found to act as a catalytic electron donor species in a variety of electron donor-acceptor complex-mediated reactions. Only substoichiometric amounts (10-25 mol %) were needed to trigger the desired reaction. The outcome could be tuned by selecting the nature of the formed radical to perform amino- and hydro-decarboxylation, dimerization, and cyclization reactions. Importantly, no external additives were needed in this reaction.",

keywords = "3-acetoxyquinuclidine, electron donor-acceptor complex, homogeneous catalysis, photochemistry, tetrachlorophthalimide",

author = "Irene Bosque and Thorsten Bach",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

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doi = "10.1021/acscatal.9b01039",

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AU - Bosque, Irene

AU - Bach, Thorsten

PY - 2019/10/4

Y1 - 2019/10/4

N2 - 3-Acetoxyquinuclidine was found to act as a catalytic electron donor species in a variety of electron donor-acceptor complex-mediated reactions. Only substoichiometric amounts (10-25 mol %) were needed to trigger the desired reaction. The outcome could be tuned by selecting the nature of the formed radical to perform amino- and hydro-decarboxylation, dimerization, and cyclization reactions. Importantly, no external additives were needed in this reaction.

AB - 3-Acetoxyquinuclidine was found to act as a catalytic electron donor species in a variety of electron donor-acceptor complex-mediated reactions. Only substoichiometric amounts (10-25 mol %) were needed to trigger the desired reaction. The outcome could be tuned by selecting the nature of the formed radical to perform amino- and hydro-decarboxylation, dimerization, and cyclization reactions. Importantly, no external additives were needed in this reaction.

KW - 3-acetoxyquinuclidine

KW - electron donor-acceptor complex

KW - homogeneous catalysis

KW - photochemistry

KW - tetrachlorophthalimide

UR - http://www.scopus.com/inward/record.url?scp=85073117064&partnerID=8YFLogxK

U2 - 10.1021/acscatal.9b01039

DO - 10.1021/acscatal.9b01039

M3 - Article

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SN - 2155-5435

VL - 9

SP - 9103

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JO - ACS Catalysis

JF - ACS Catalysis

IS - 10

ER -

3-Acetoxyquinuclidine as Catalyst in Electron Donor-Acceptor Complex-Mediated Reactions Triggered by Visible Light

Abstract

Keywords

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