2,3-Bis(diphenylphosphynyl)-1,3-butadiene via a double [2,3]-sigmatropic rearrangement. A reinvestigation of the reaction of 2-butyne-1,4-diol with chlorodiphenylphosphine

T. Pollok; H. Schmidbaur

doi:10.1016/S0040-4039(00)95917-3

2,3-Bis(diphenylphosphynyl)-1,3-butadiene via a double [2,3]-sigmatropic rearrangement. A reinvestigation of the reaction of 2-butyne-1,4-diol with chlorodiphenylphosphine

T. Pollok, H. Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

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Abstract

Contrary to previous reports, the reaction of 2-butyne-1,4-diol with chlorodiphenylphosphine yields 2,3-bis(diphenylphosphinyl)-1,3-butadiene 3 instead of the 1,4-isomer. The structure of the product has been elucidated from ¹H, ¹³C and ³¹P-NMR spectroscopic data.

Original language	English
Pages (from-to)	1085-1088
Number of pages	4
Journal	Tetrahedron Letters
Volume	28
Issue number	10
DOIs	https://doi.org/10.1016/S0040-4039(00)95917-3
State	Published - 1987

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title = "2,3-Bis(diphenylphosphynyl)-1,3-butadiene via a double [2,3]-sigmatropic rearrangement. A reinvestigation of the reaction of 2-butyne-1,4-diol with chlorodiphenylphosphine",

abstract = "Contrary to previous reports, the reaction of 2-butyne-1,4-diol with chlorodiphenylphosphine yields 2,3-bis(diphenylphosphinyl)-1,3-butadiene 3 instead of the 1,4-isomer. The structure of the product has been elucidated from 1H, 13C and 31P-NMR spectroscopic data.",

author = "T. Pollok and H. Schmidbaur",

year = "1987",

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journal = "Tetrahedron Letters",

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T1 - 2,3-Bis(diphenylphosphynyl)-1,3-butadiene via a double [2,3]-sigmatropic rearrangement. A reinvestigation of the reaction of 2-butyne-1,4-diol with chlorodiphenylphosphine

AU - Pollok, T.

AU - Schmidbaur, H.

PY - 1987

Y1 - 1987

N2 - Contrary to previous reports, the reaction of 2-butyne-1,4-diol with chlorodiphenylphosphine yields 2,3-bis(diphenylphosphinyl)-1,3-butadiene 3 instead of the 1,4-isomer. The structure of the product has been elucidated from 1H, 13C and 31P-NMR spectroscopic data.

AB - Contrary to previous reports, the reaction of 2-butyne-1,4-diol with chlorodiphenylphosphine yields 2,3-bis(diphenylphosphinyl)-1,3-butadiene 3 instead of the 1,4-isomer. The structure of the product has been elucidated from 1H, 13C and 31P-NMR spectroscopic data.

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U2 - 10.1016/S0040-4039(00)95917-3

DO - 10.1016/S0040-4039(00)95917-3

M3 - Article

AN - SCOPUS:0343534718

SN - 0040-4039

VL - 28

SP - 1085

EP - 1088

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 10

ER -

2,3-Bis(diphenylphosphynyl)-1,3-butadiene via a double [2,3]-sigmatropic rearrangement. A reinvestigation of the reaction of 2-butyne-1,4-diol with chlorodiphenylphosphine

Abstract

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