[2 + 2]‐Cycloaddition eines Iminoborans an einen Methylen‐Titan‐Komplex

Peter Paetzold, Klaus Delpy, Russel P. Hughes, Wolfgang A. Herrmann

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Abstract

[2 + 2]‐Cycloaddition of an Iminoborane to a Methylene‐Titanium Coordination Compound The iminoborane tBuB  NtBu (1c) reacts with the short‐lived titanaethene H2C  TiCp2 (3) to give the 1‐aza‐2‐bora‐4‐titanacyclobutane 4c by [2 + 2]‐cycloaddition. A corresponding reaction with the more reactive iminoboranes 1a, b, d is indicated by NMR data.

Original languageGerman
Pages (from-to)1724-1725
Number of pages2
JournalChemische Berichte
Volume118
Issue number4
DOIs
StatePublished - Apr 1985
Externally publishedYes

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