18-membered heterometallacyclic gold(I) compounds: Structural influences of Co-crystallized solvent

Liliana Dobrzańska, Christoph E. Strasser, Hubert Schmidbaur, Helgard G. Raubenheimer

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

5-Lithiated 4,4-dimethyl-2-(2-thienyl)oxazoline reacted by halide and tetrahydrothiophene (THT) substitution with [AuCl(THT)] to form a cyclic trinuclear compound (1) in satisfactory yield. Spectroscopic studies and single-crystal X-ray analyses clarified the bonding within the ring system. The structure determination of two THF solvates revealed differences in the supramolecular assembly of the constituting molecules.

Original languageEnglish
Pages (from-to)1115-1122
Number of pages8
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume67
Issue number10
DOIs
StatePublished - Oct 2012
Externally publishedYes

Keywords

  • Carbene character
  • Crystal modification
  • Gold
  • Heterometallacylic complexes
  • Thienyl oxazoline

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