1,3,2λ5‐Benzothiazaphosphole 2‐Oxide and 1,3,2λ5‐benzoxazaphosphole 2‐oxide derivatives, new and versatile phosphorylating reagents

Peter Jacob; Wolfgang Richter; Ivar Ugi

doi:10.1002/jlac.199119910195

1,3,2λ⁵‐Benzothiazaphosphole 2‐Oxide and 1,3,2λ⁵‐benzoxazaphosphole 2‐oxide derivatives, new and versatile phosphorylating reagents

Peter Jacob, Wolfgang Richter, Ivar Ugi

Chair of Aquatic Systems Biology - Location Iffeldorf

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The synthesis of the highly reactive five‐membered cyclic phosphorylating reagents 6a and 12 is described. The reagent 6a monophosphorylates alcohols without ring opening, whereas 12 diphosphorylates with ring opening yielding phosphate triesters.

Original language	English
Pages (from-to)	519-522
Number of pages	4
Journal	Liebigs Annalen der Chemie
Volume	1991
Issue number	6
DOIs	https://doi.org/10.1002/jlac.199119910195
State	Published - 1991

Keywords

1,3,2λ‐Benzothiazaphosphole 2‐oxide
1,3,2λ‐Benzoxazaphosphole 2‐oxide
Phosphorylating reagents, cyclic five‐membered

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10.1002/jlac.199119910195

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title = "1,3,2λ5‐Benzothiazaphosphole 2‐Oxide and 1,3,2λ5‐benzoxazaphosphole 2‐oxide derivatives, new and versatile phosphorylating reagents",

abstract = "The synthesis of the highly reactive five‐membered cyclic phosphorylating reagents 6a and 12 is described. The reagent 6a monophosphorylates alcohols without ring opening, whereas 12 diphosphorylates with ring opening yielding phosphate triesters.",

keywords = "1,3,2λ‐Benzothiazaphosphole 2‐oxide, 1,3,2λ‐Benzoxazaphosphole 2‐oxide, Phosphorylating reagents, cyclic five‐membered",

author = "Peter Jacob and Wolfgang Richter and Ivar Ugi",

year = "1991",

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language = "English",

volume = "1991",

pages = "519--522",

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T1 - 1,3,2λ5‐Benzothiazaphosphole 2‐Oxide and 1,3,2λ5‐benzoxazaphosphole 2‐oxide derivatives, new and versatile phosphorylating reagents

AU - Jacob, Peter

AU - Richter, Wolfgang

AU - Ugi, Ivar

PY - 1991

Y1 - 1991

N2 - The synthesis of the highly reactive five‐membered cyclic phosphorylating reagents 6a and 12 is described. The reagent 6a monophosphorylates alcohols without ring opening, whereas 12 diphosphorylates with ring opening yielding phosphate triesters.

AB - The synthesis of the highly reactive five‐membered cyclic phosphorylating reagents 6a and 12 is described. The reagent 6a monophosphorylates alcohols without ring opening, whereas 12 diphosphorylates with ring opening yielding phosphate triesters.

KW - 1,3,2λ‐Benzothiazaphosphole 2‐oxide

KW - 1,3,2λ‐Benzoxazaphosphole 2‐oxide

KW - Phosphorylating reagents, cyclic five‐membered

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U2 - 10.1002/jlac.199119910195

DO - 10.1002/jlac.199119910195

M3 - Article

AN - SCOPUS:84986730888

SN - 0170-2041

VL - 1991

SP - 519

EP - 522

JO - Liebigs Annalen der Chemie

JF - Liebigs Annalen der Chemie

IS - 6

ER -

1,3,2λ⁵‐Benzothiazaphosphole 2‐Oxide and 1,3,2λ⁵‐benzoxazaphosphole 2‐oxide derivatives, new and versatile phosphorylating reagents

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Keywords

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