1/1-komplexe des trimethylphosphinimino-pentamethyldisiloxans und des bis(trimethylphosphinimino)-dimethylsilans mit aluminium-, gallium- und indiumtrimethy. Verbindungen mit stationärem bzw. Oszillierendem akzeptor

W. Wolfsberger, H. Schmidbaur

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Abstract

(CH3)3P&zdbnd;NSi(CH3)2OSi(CH3)3 reacts with (CH3)3Al, (CH33Ga, or (CH3)3In to give rigid 1/1-adducts. On the contrary, the analogous 1/1-complexes of(CH3)3P&.zdbndNSi(CH3)2-N&.zdbndP(CH3)3 exhibit a nonrigid behavior as shown by the temperature dependence of the 1H NMR spectra.

Original languageGerman
Pages (from-to)5-12
Number of pages8
JournalJournal of Organometallic Chemistry
Volume122
Issue number1
DOIs
StatePublished - 7 Dec 1976
Externally publishedYes

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