[(η5‐C5Me5)Re(CH3)4], the First Organorhenium(V) Compound without Heteroatom Ligands

Martina Flöel; Eberhardt Herdtweck; Werner Wagner; Jürgen Kulpe; Peter Härter; Wolfgang A. Herrmann

doi:10.1002/anie.198707871

[(η⁵‐C₅Me₅)Re(CH₃)₄], the First Organorhenium(V) Compound without Heteroatom Ligands

Martina Flöel
, Eberhardt Herdtweck
, Werner Wagner
, Jürgen Kulpe
, Peter Härter
, Wolfgang A. Herrmann

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Extreme light, air, and moisture sensitivity characterize the title compounds 1, h which form brilliant red crystalline platelets that are stable for long periods of time at dry‐ice temperature. They were obtained by reaction of CH₃MgCl with (C₅Me₅)ReCl₄ in a molar ratio of 4:1 (yields 40–50%). The paramagnetic complex 1 has a tetragonalpyramidal molecular structure. (Figure Presented.)

Original language	English
Pages (from-to)	787-789
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	26
Issue number	8
DOIs	https://doi.org/10.1002/anie.198707871
State	Published - Aug 1987

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title = "[(η5‐C5Me5)Re(CH3)4], the First Organorhenium(V) Compound without Heteroatom Ligands",

abstract = "Extreme light, air, and moisture sensitivity characterize the title compounds 1, h which form brilliant red crystalline platelets that are stable for long periods of time at dry‐ice temperature. They were obtained by reaction of CH3MgCl with (C5Me5)ReCl4 in a molar ratio of 4:1 (yields 40–50\%). The paramagnetic complex 1 has a tetragonalpyramidal molecular structure. (Figure Presented.)",

author = "Martina Fl{\"o}el and Eberhardt Herdtweck and Werner Wagner and J{\"u}rgen Kulpe and Peter H{\"a}rter and Herrmann, \{Wolfgang A.\}",

year = "1987",

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doi = "10.1002/anie.198707871",

language = "English",

volume = "26",

pages = "787--789",

journal = "Angewandte Chemie International Edition in English",

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T1 - [(η5‐C5Me5)Re(CH3)4], the First Organorhenium(V) Compound without Heteroatom Ligands

AU - Flöel, Martina

AU - Herdtweck, Eberhardt

AU - Wagner, Werner

AU - Kulpe, Jürgen

AU - Härter, Peter

AU - Herrmann, Wolfgang A.

PY - 1987/8

Y1 - 1987/8

N2 - Extreme light, air, and moisture sensitivity characterize the title compounds 1, h which form brilliant red crystalline platelets that are stable for long periods of time at dry‐ice temperature. They were obtained by reaction of CH3MgCl with (C5Me5)ReCl4 in a molar ratio of 4:1 (yields 40–50%). The paramagnetic complex 1 has a tetragonalpyramidal molecular structure. (Figure Presented.)

AB - Extreme light, air, and moisture sensitivity characterize the title compounds 1, h which form brilliant red crystalline platelets that are stable for long periods of time at dry‐ice temperature. They were obtained by reaction of CH3MgCl with (C5Me5)ReCl4 in a molar ratio of 4:1 (yields 40–50%). The paramagnetic complex 1 has a tetragonalpyramidal molecular structure. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84985610075

U2 - 10.1002/anie.198707871

DO - 10.1002/anie.198707871

M3 - Article

AN - SCOPUS:84985610075

SN - 0570-0833

VL - 26

SP - 787

EP - 789

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 8

ER -

[(η⁵‐C₅Me₅)Re(CH₃)₄], the First Organorhenium(V) Compound without Heteroatom Ligands

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