TY - JOUR
T1 - [(η5‐C5Me5)Re(CH3)4], the First Organorhenium(V) Compound without Heteroatom Ligands
AU - Flöel, Martina
AU - Herdtweck, Eberhardt
AU - Wagner, Werner
AU - Kulpe, Jürgen
AU - Härter, Peter
AU - Herrmann, Wolfgang A.
PY - 1987/8
Y1 - 1987/8
N2 - Extreme light, air, and moisture sensitivity characterize the title compounds 1, h which form brilliant red crystalline platelets that are stable for long periods of time at dry‐ice temperature. They were obtained by reaction of CH3MgCl with (C5Me5)ReCl4 in a molar ratio of 4:1 (yields 40–50%). The paramagnetic complex 1 has a tetragonalpyramidal molecular structure. (Figure Presented.)
AB - Extreme light, air, and moisture sensitivity characterize the title compounds 1, h which form brilliant red crystalline platelets that are stable for long periods of time at dry‐ice temperature. They were obtained by reaction of CH3MgCl with (C5Me5)ReCl4 in a molar ratio of 4:1 (yields 40–50%). The paramagnetic complex 1 has a tetragonalpyramidal molecular structure. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=84985610075&partnerID=8YFLogxK
U2 - 10.1002/anie.198707871
DO - 10.1002/anie.198707871
M3 - Article
AN - SCOPUS:84985610075
SN - 0570-0833
VL - 26
SP - 787
EP - 789
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 8
ER -