η5,η1-Coordinated cyclopentadienyl transition metal complexes featuring σ-metal-carbon ansa bridges

Alexander Raith; Philipp Altmann; Mirza Cokoja; Wolfgang A. Herrmann; Fritz E. Kühn

doi:10.1016/j.ccr.2009.09.008

η⁵,η¹-Coordinated cyclopentadienyl transition metal complexes featuring σ-metal-carbon ansa bridges

Alexander Raith, Philipp Altmann, Mirza Cokoja, Wolfgang A. Herrmann, Fritz E. Kühn

Technical University of Munich

Research output: Contribution to journal › Review article › peer-review

45 Scopus citations

Abstract

An overview of η⁵,η¹-coordinated transition metal ansa complexes is given. These compounds bear one or more coordinated cyclopentadienyl moieties connected with a η¹-bridging σ-bonded carbon chain featuring a length of at least two carbon atoms. Synthetic approaches, as well as characterisation and applications are described.

Original language	English
Pages (from-to)	608-634
Number of pages	27
Journal	Coordination Chemistry Reviews
Volume	254
Issue number	5-6
DOIs	https://doi.org/10.1016/j.ccr.2009.09.008
State	Published - Mar 2010

Keywords

Ansa compounds
Catalyst design
Constrained geometry catalysts
Epoxidation
Transition metals

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10.1016/j.ccr.2009.09.008

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abstract = "An overview of η5,η1-coordinated transition metal ansa complexes is given. These compounds bear one or more coordinated cyclopentadienyl moieties connected with a η1-bridging σ-bonded carbon chain featuring a length of at least two carbon atoms. Synthetic approaches, as well as characterisation and applications are described.",

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AU - Raith, Alexander

AU - Altmann, Philipp

AU - Cokoja, Mirza

AU - Herrmann, Wolfgang A.

AU - Kühn, Fritz E.

PY - 2010/3

Y1 - 2010/3

N2 - An overview of η5,η1-coordinated transition metal ansa complexes is given. These compounds bear one or more coordinated cyclopentadienyl moieties connected with a η1-bridging σ-bonded carbon chain featuring a length of at least two carbon atoms. Synthetic approaches, as well as characterisation and applications are described.

AB - An overview of η5,η1-coordinated transition metal ansa complexes is given. These compounds bear one or more coordinated cyclopentadienyl moieties connected with a η1-bridging σ-bonded carbon chain featuring a length of at least two carbon atoms. Synthetic approaches, as well as characterisation and applications are described.

KW - Ansa compounds

KW - Catalyst design

KW - Constrained geometry catalysts

KW - Epoxidation

KW - Transition metals

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U2 - 10.1016/j.ccr.2009.09.008

DO - 10.1016/j.ccr.2009.09.008

M3 - Review article

AN - SCOPUS:72149134482

SN - 0010-8545

VL - 254

SP - 608

EP - 634

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

IS - 5-6

ER -

η⁵,η¹-Coordinated cyclopentadienyl transition metal complexes featuring σ-metal-carbon ansa bridges

Abstract

Keywords

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