Übergangsmetallsubstituierte gallane: Synthese, struktur und bindungsverhältnisse von [(CO)4CoGaEt2(NC7H13)], [(PMe3)(CO)3CoGaCl2(NMe3)], [(CO)4CoGaCl3]K und [(CO)5MnGaEt2(NC7H13)]

Roland A. Fischer; Alexander Miehr; Holger Hoffmann; Wolfram Rogge; Christian Boehme; Gernot Frenking; Eberhardt Herdtweck

doi:10.1002/(SICI)1521-3749(199909)625:9<1466::AID-ZAAC1466<3.0.CO;2-O

Übergangsmetallsubstituierte gallane: Synthese, struktur und bindungsverhältnisse von [(CO)₄CoGaEt₂(NC₇H₁₃)], [(PMe₃)(CO)₃CoGaCl₂(NMe₃)], [(CO)₄CoGaCl₃]K und [(CO)₅MnGaEt₂(NC₇H₁₃)]

Translated title of the contribution: Transition metal substituted gallanes: Synthesis and x-ray structures of [(CO)₄CoGaEt₂(NC₇H₁₃)], [(PMe₃)(CO)₃CoGaCl₂(NMe₃)], [(CO)₄CoGaCl₃]K, and [(CO)₅MnGaEt₂(NC₇H₁₃)]

Roland A. Fischer
, Alexander Miehr
, Holger Hoffmann
, Wolfram Rogge
, Christian Boehme
, Gernot Frenking
, Eberhardt Herdtweck

Max-Planck-lnstitut für Kohlenforschung
Philipps-Universität Marburg
Technical University of Munich

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The transition metal substituted gallanes [(CO)₅MnGaEt₂(NC₇H₁₃)] (1), [(PMe₃)(CO)₃CoGaCl₂ · (NMe₃)] (2), [(CO)₄CoGaEt₂(NC₇H₁₃)] (3), and [(CO)₄CoGaCl₃]K (4) were obtained by the reaction of the potassium/sodium salts of the manganese-and cobalt-carbonylmetallates with the chlorogallium species ClGaEt₂(NC₇H₁₃), Cl₃Ga(NMe₃), and GaCl₃. The structures were established by single crystal X-ray analysis 1: space group P2_l1/c (I.T.-No.: 14); Z = 4; a = 1425.4(2) pm, b= 1007.4(1 )pm, c = 1429.9(3) pm; β = 113.92(1)°; 2: space group P2_l/m (I.T.-No.: 11); Z = 2; a = 746.1(1) pm, b = 1131.2(1) pm, c = 1061.5(1) pm; β = 101.87(1)°; 3: space group P2_l/c (I.T.-No.: 14); Z = 8; a = 1405.9(2) pm, b = 1786.2(2) pm, c = 1430.9(2) pm; β = 91.47(1)°; 4: space group P2_l/c; Z = 4; a = 1185.7(1) pm, b = 895.4(1) pm, c = 1144.7(3) pm; β = 106.47(2)°. The model compounds [{L′(CO)₃Co}GaX₂L] (L′= CO, PH₃; L = NH₃, X = H, Cl) with polar σ(Co-Ga) bonds and the effect of the substituent on the bond length are characterized with DFT-calculations.

Translated title of the contribution	Transition metal substituted gallanes: Synthesis and x-ray structures of [(CO)₄CoGaEt₂(NC₇H₁₃)], [(PMe₃)(CO)₃CoGaCl₂(NMe₃)], [(CO)₄CoGaCl₃]K, and [(CO)₅MnGaEt₂(NC₇H₁₃)]
Original language	German
Pages (from-to)	1466-1474
Number of pages	9
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	625
Issue number	9
DOIs	https://doi.org/10.1002/(SICI)1521-3749(199909)625:9<1466::AID-ZAAC1466<3.0.CO;2-O
State	Published - 1999
Externally published	Yes

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10.1002/(SICI)1521-3749(199909)625:9<1466::AID-ZAAC1466<3.0.CO;2-O

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Fischer, R. A., Miehr, A., Hoffmann, H., Rogge, W., Boehme, C., Frenking, G., & Herdtweck, E. (1999). Übergangsmetallsubstituierte gallane: Synthese, struktur und bindungsverhältnisse von [(CO)₄CoGaEt₂(NC₇H₁₃)], [(PMe₃)(CO)₃CoGaCl₂(NMe₃)], [(CO)₄CoGaCl₃]K und [(CO)₅MnGaEt₂(NC₇H₁₃)]. Zeitschrift fur Anorganische und Allgemeine Chemie, 625(9), 1466-1474. https://doi.org/10.1002/(SICI)1521-3749(199909)625:9<1466::AID-ZAAC1466<3.0.CO;2-O

@article{09ad85dd22cc45af86eb2d213d423c2c,

title = "{\"U}bergangsmetallsubstituierte gallane: Synthese, struktur und bindungsverh{\"a}ltnisse von [(CO)4CoGaEt2(NC7H13)], [(PMe3)(CO)3CoGaCl2(NMe3)], [(CO)4CoGaCl3]K und [(CO)5MnGaEt2(NC7H13)]",

abstract = "The transition metal substituted gallanes [(CO)5MnGaEt2(NC7H13)] (1), [(PMe3)(CO)3CoGaCl2 · (NMe3)] (2), [(CO)4CoGaEt2(NC7H13)] (3), and [(CO)4CoGaCl3]K (4) were obtained by the reaction of the potassium/sodium salts of the manganese-and cobalt-carbonylmetallates with the chlorogallium species ClGaEt2(NC7H13), Cl3Ga(NMe3), and GaCl3. The structures were established by single crystal X-ray analysis 1: space group P2l1/c (I.T.-No.: 14); Z = 4; a = 1425.4(2) pm, b= 1007.4(1 )pm, c = 1429.9(3) pm; β = 113.92(1)°; 2: space group P2l/m (I.T.-No.: 11); Z = 2; a = 746.1(1) pm, b = 1131.2(1) pm, c = 1061.5(1) pm; β = 101.87(1)°; 3: space group P2l/c (I.T.-No.: 14); Z = 8; a = 1405.9(2) pm, b = 1786.2(2) pm, c = 1430.9(2) pm; β = 91.47(1)°; 4: space group P2l/c; Z = 4; a = 1185.7(1) pm, b = 895.4(1) pm, c = 1144.7(3) pm; β = 106.47(2)°. The model compounds [\{L′(CO)3Co\}GaX2L] (L′= CO, PH3; L = NH3, X = H, Cl) with polar σ(Co-Ga) bonds and the effect of the substituent on the bond length are characterized with DFT-calculations.",

keywords = "Cobalt Gallium compounds, Density functional calculations, Manganese Gallium compounds, X-ray structures, σ(Co-Ga) bonds",

author = "Fischer, \{Roland A.\} and Alexander Miehr and Holger Hoffmann and Wolfram Rogge and Christian Boehme and Gernot Frenking and Eberhardt Herdtweck",

year = "1999",

doi = "10.1002/(SICI)1521-3749(199909)625:9<1466::AID-ZAAC1466<3.0.CO;2-O",

language = "Deutsch",

volume = "625",

pages = "1466--1474",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "9",

}

Fischer, RA, Miehr, A, Hoffmann, H, Rogge, W, Boehme, C, Frenking, G & Herdtweck, E 1999, 'Übergangsmetallsubstituierte gallane: Synthese, struktur und bindungsverhältnisse von [(CO)₄CoGaEt₂(NC₇H₁₃)], [(PMe₃)(CO)₃CoGaCl₂(NMe₃)], [(CO)₄CoGaCl₃]K und [(CO)₅MnGaEt₂(NC₇H₁₃)]', Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 625, no. 9, pp. 1466-1474. https://doi.org/10.1002/(SICI)1521-3749(199909)625:9<1466::AID-ZAAC1466<3.0.CO;2-O

Übergangsmetallsubstituierte gallane: Synthese, struktur und bindungsverhältnisse von [(CO)₄CoGaEt₂(NC₇H₁₃)], [(PMe₃)(CO)₃CoGaCl₂(NMe₃)], [(CO)₄CoGaCl₃]K und [(CO)₅MnGaEt₂(NC₇H₁₃)]. / Fischer, Roland A.; Miehr, Alexander; Hoffmann, Holger et al.
In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 625, No. 9, 1999, p. 1466-1474.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Übergangsmetallsubstituierte gallane

T2 - Synthese, struktur und bindungsverhältnisse von [(CO)4CoGaEt2(NC7H13)], [(PMe3)(CO)3CoGaCl2(NMe3)], [(CO)4CoGaCl3]K und [(CO)5MnGaEt2(NC7H13)]

AU - Fischer, Roland A.

AU - Miehr, Alexander

AU - Hoffmann, Holger

AU - Rogge, Wolfram

AU - Boehme, Christian

AU - Frenking, Gernot

AU - Herdtweck, Eberhardt

PY - 1999

Y1 - 1999

N2 - The transition metal substituted gallanes [(CO)5MnGaEt2(NC7H13)] (1), [(PMe3)(CO)3CoGaCl2 · (NMe3)] (2), [(CO)4CoGaEt2(NC7H13)] (3), and [(CO)4CoGaCl3]K (4) were obtained by the reaction of the potassium/sodium salts of the manganese-and cobalt-carbonylmetallates with the chlorogallium species ClGaEt2(NC7H13), Cl3Ga(NMe3), and GaCl3. The structures were established by single crystal X-ray analysis 1: space group P2l1/c (I.T.-No.: 14); Z = 4; a = 1425.4(2) pm, b= 1007.4(1 )pm, c = 1429.9(3) pm; β = 113.92(1)°; 2: space group P2l/m (I.T.-No.: 11); Z = 2; a = 746.1(1) pm, b = 1131.2(1) pm, c = 1061.5(1) pm; β = 101.87(1)°; 3: space group P2l/c (I.T.-No.: 14); Z = 8; a = 1405.9(2) pm, b = 1786.2(2) pm, c = 1430.9(2) pm; β = 91.47(1)°; 4: space group P2l/c; Z = 4; a = 1185.7(1) pm, b = 895.4(1) pm, c = 1144.7(3) pm; β = 106.47(2)°. The model compounds [{L′(CO)3Co}GaX2L] (L′= CO, PH3; L = NH3, X = H, Cl) with polar σ(Co-Ga) bonds and the effect of the substituent on the bond length are characterized with DFT-calculations.

AB - The transition metal substituted gallanes [(CO)5MnGaEt2(NC7H13)] (1), [(PMe3)(CO)3CoGaCl2 · (NMe3)] (2), [(CO)4CoGaEt2(NC7H13)] (3), and [(CO)4CoGaCl3]K (4) were obtained by the reaction of the potassium/sodium salts of the manganese-and cobalt-carbonylmetallates with the chlorogallium species ClGaEt2(NC7H13), Cl3Ga(NMe3), and GaCl3. The structures were established by single crystal X-ray analysis 1: space group P2l1/c (I.T.-No.: 14); Z = 4; a = 1425.4(2) pm, b= 1007.4(1 )pm, c = 1429.9(3) pm; β = 113.92(1)°; 2: space group P2l/m (I.T.-No.: 11); Z = 2; a = 746.1(1) pm, b = 1131.2(1) pm, c = 1061.5(1) pm; β = 101.87(1)°; 3: space group P2l/c (I.T.-No.: 14); Z = 8; a = 1405.9(2) pm, b = 1786.2(2) pm, c = 1430.9(2) pm; β = 91.47(1)°; 4: space group P2l/c; Z = 4; a = 1185.7(1) pm, b = 895.4(1) pm, c = 1144.7(3) pm; β = 106.47(2)°. The model compounds [{L′(CO)3Co}GaX2L] (L′= CO, PH3; L = NH3, X = H, Cl) with polar σ(Co-Ga) bonds and the effect of the substituent on the bond length are characterized with DFT-calculations.

KW - Cobalt Gallium compounds

KW - Density functional calculations

KW - Manganese Gallium compounds

KW - X-ray structures

KW - σ(Co-Ga) bonds

UR - https://www.scopus.com/pages/publications/0000986692

U2 - 10.1002/(SICI)1521-3749(199909)625:9<1466::AID-ZAAC1466<3.0.CO;2-O

DO - 10.1002/(SICI)1521-3749(199909)625:9<1466::AID-ZAAC1466<3.0.CO;2-O

M3 - Artikel

AN - SCOPUS:0000986692

SN - 0044-2313

VL - 625

SP - 1466

EP - 1474

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 9

ER -

Fischer RA, Miehr A, Hoffmann H, Rogge W, Boehme C, Frenking G et al. Übergangsmetallsubstituierte gallane: Synthese, struktur und bindungsverhältnisse von [(CO)₄CoGaEt₂(NC₇H₁₃)], [(PMe₃)(CO)₃CoGaCl₂(NMe₃)], [(CO)₄CoGaCl₃]K und [(CO)₅MnGaEt₂(NC₇H₁₃)]. Zeitschrift fur Anorganische und Allgemeine Chemie. 1999;625(9):1466-1474. doi: 10.1002/(SICI)1521-3749(199909)625:9<1466::AID-ZAAC1466<3.0.CO;2-O

Übergangsmetallsubstituierte gallane: Synthese, struktur und bindungsverhältnisse von [(CO)₄CoGaEt₂(NC₇H₁₃)], [(PMe₃)(CO)₃CoGaCl₂(NMe₃)], [(CO)₄CoGaCl₃]K und [(CO)₅MnGaEt₂(NC₇H₁₃)]

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