TY - JOUR
T1 - Übergangsmetall-Methylen-Komplexe. XXXVII. Addition von Methylen und Diazomethan an eine Metall-Metall-Dreifachbindung
AU - Herrmann, Wolfgang A.
AU - Bell, Linda K.
PY - 1982/11/23
Y1 - 1982/11/23
N2 - Upon reaction of the dimolybdenum complex (η5-C5Me5)2Mo2(CO)4 (1) with excess diazomethane (2) both the methylene fragment, CH2, and its diazo precursor, N2 CH2, add to the unsaturated metal-metal triple bond. The thermally labile product of composition (η5-C5Me5)2Mo2(CO)4 (CH2)(CH2N2) (3) was shown by IR, 1H and 13C NMR spectroscopy to reveal two (η5-C5Me5)Mo(CO)2 moieties held together by CH2 and CH2N2 bridging ligands.
AB - Upon reaction of the dimolybdenum complex (η5-C5Me5)2Mo2(CO)4 (1) with excess diazomethane (2) both the methylene fragment, CH2, and its diazo precursor, N2 CH2, add to the unsaturated metal-metal triple bond. The thermally labile product of composition (η5-C5Me5)2Mo2(CO)4 (CH2)(CH2N2) (3) was shown by IR, 1H and 13C NMR spectroscopy to reveal two (η5-C5Me5)Mo(CO)2 moieties held together by CH2 and CH2N2 bridging ligands.
UR - https://www.scopus.com/pages/publications/26144451691
U2 - 10.1016/S0022-328X(00)95269-0
DO - 10.1016/S0022-328X(00)95269-0
M3 - Article
AN - SCOPUS:26144451691
SN - 0022-328X
VL - 239
SP - C4-C8
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -