Übergangsmetall-methylen-komplexe. XXX. Stufenweiser aufbau von methylen-brücken durch carben-addition an metall-metall-doppelbindungen

Wolfgang A. Herrmann; John M. Huggins; Christine Bauer; Martina Smischek; Heike Pfisterer; Manfred L. Ziegler

doi:10.1016/S0022-328X(00)83416-6

Übergangsmetall-methylen-komplexe. XXX. Stufenweiser aufbau von methylen-brücken durch carben-addition an metall-metall-doppelbindungen

Wolfgang A. Herrmann
, John M. Huggins
, Christine Bauer
, Martina Smischek
, Heike Pfisterer
, Manfred L. Ziegler

University of Regensburg
Heidelberg University

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

A simple, high-yield synthetic route to otherwise inaccessible multiply bridged organometallic compounds having carbonyl, alkylidene and sulfur dioxide bridges is exemplified by the reactivity of bis[μ-carbonyl(η⁵-pentamethylcyclopentadienyl)cobalt] (Co-Co) towards diazoalkanes and sulfur-dioxide.

Original language	French
Pages (from-to)	C59-C64
Journal	Journal of Organometallic Chemistry
Volume	226
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)83416-6
State	Published - 2 Mar 1982
Externally published	Yes

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10.1016/S0022-328X(00)83416-6

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title = "{\"U}bergangsmetall-methylen-komplexe. XXX. Stufenweiser aufbau von methylen-br{\"u}cken durch carben-addition an metall-metall-doppelbindungen",

abstract = "A simple, high-yield synthetic route to otherwise inaccessible multiply bridged organometallic compounds having carbonyl, alkylidene and sulfur dioxide bridges is exemplified by the reactivity of bis[μ-carbonyl(η5-pentamethylcyclopentadienyl)cobalt] (Co-Co) towards diazoalkanes and sulfur-dioxide.",

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doi = "10.1016/S0022-328X(00)83416-6",

language = "French",

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T1 - Übergangsmetall-methylen-komplexe. XXX. Stufenweiser aufbau von methylen-brücken durch carben-addition an metall-metall-doppelbindungen

AU - Herrmann, Wolfgang A.

AU - Huggins, John M.

AU - Bauer, Christine

AU - Smischek, Martina

AU - Pfisterer, Heike

AU - Ziegler, Manfred L.

PY - 1982/3/2

Y1 - 1982/3/2

N2 - A simple, high-yield synthetic route to otherwise inaccessible multiply bridged organometallic compounds having carbonyl, alkylidene and sulfur dioxide bridges is exemplified by the reactivity of bis[μ-carbonyl(η5-pentamethylcyclopentadienyl)cobalt] (Co-Co) towards diazoalkanes and sulfur-dioxide.

AB - A simple, high-yield synthetic route to otherwise inaccessible multiply bridged organometallic compounds having carbonyl, alkylidene and sulfur dioxide bridges is exemplified by the reactivity of bis[μ-carbonyl(η5-pentamethylcyclopentadienyl)cobalt] (Co-Co) towards diazoalkanes and sulfur-dioxide.

UR - https://www.scopus.com/pages/publications/49049133987

U2 - 10.1016/S0022-328X(00)83416-6

DO - 10.1016/S0022-328X(00)83416-6

M3 - Article

AN - SCOPUS:49049133987

SN - 0022-328X

VL - 226

SP - C59-C64

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Übergangsmetall-methylen-komplexe. XXX. Stufenweiser aufbau von methylen-brücken durch carben-addition an metall-metall-doppelbindungen

Abstract

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