TY - JOUR
T1 - Übergangsmetall-methylen-komplexe. XVII. Carben-addition an eine FeFe-bindung
T2 - synthese des ersten μ-methylen(nitrosyl)-komplexes
AU - Herrmann, Wolfgang A.
AU - Bauer, Christine
PY - 1981/1/13
Y1 - 1981/1/13
N2 - The diazoalkane method has been utilized for the simple synthesis of the first known example of a μ-methylene(nitrosyl) complex: bis[(η5-cyclopentadienyl)(μ-nitrosyl)iron](FeFe) (I) which reacts with diazomethane (II) in the temperature range -80 to +25°C to give μ-methylenebis[(η5-cyclopentadienyl)nitrosyliron](FeFe) (III) as a black, crystalline, air-stable compound which was characterized by elemental analysis, IR, 1H NMR and mass spectra. The successful synthesis of III points to the general applicability of the carbene addition reaction onto metal-metal multiple bonds.
AB - The diazoalkane method has been utilized for the simple synthesis of the first known example of a μ-methylene(nitrosyl) complex: bis[(η5-cyclopentadienyl)(μ-nitrosyl)iron](FeFe) (I) which reacts with diazomethane (II) in the temperature range -80 to +25°C to give μ-methylenebis[(η5-cyclopentadienyl)nitrosyliron](FeFe) (III) as a black, crystalline, air-stable compound which was characterized by elemental analysis, IR, 1H NMR and mass spectra. The successful synthesis of III points to the general applicability of the carbene addition reaction onto metal-metal multiple bonds.
UR - https://www.scopus.com/pages/publications/4243483428
U2 - 10.1016/S0022-328X(00)84596-9
DO - 10.1016/S0022-328X(00)84596-9
M3 - Artikel
AN - SCOPUS:4243483428
SN - 0022-328X
VL - 204
SP - C21-C24
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -